典型文献
Rhodium catalyzed asymmetric synthesis of Chiraphos derivatives
文献摘要：
Herein,we report a highly efficient versatile synthetic route to Chiraphos derivatives through Rh/Ph-bod catalyzed asymmetric addition of aryl boronic acids to phosphinyl dienes.Various substituted phosphinyl dienes,both on the parent skeleton and the phosphine atoms,were well tolerated with this method and provided chiral phosphine oxides in satisfied yield and up to 95％ee.The corresponding Chiraphos deriva-tive displayed an advantage over Chiraphos in the representative Pd-catalyzed asymmetric 1,4-addition reaction.
文献关键词：
中图分类号：
作者姓名：
Ying-Ying Sun;Bin Zhang;Liangbin Yu;Ranran Cui;Qingyang Zhao;Qing-Wei Zhang
作者机构：
Department of Chemistry,University of Science and Technology of China,Heifei 230026,China;School of Pharmaceutical Sciences(Shenzhen),Shenzhen Campus of Sun Yat-sen University,Shenzhen 518107,China
文献出处：
引用格式：
[1]Ying-Ying Sun;Bin Zhang;Liangbin Yu;Ranran Cui;Qingyang Zhao;Qing-Wei Zhang-.Rhodium catalyzed asymmetric synthesis of Chiraphos derivatives)[J].中国化学快报（英文版）,2022(12):5084-5087
A类：
Chiraphos,phosphinyl
B类：
Rhodium,catalyzed,asymmetric,synthesis,derivatives,Herein,report,highly,efficient,versatile,synthetic,route,through,Ph,bod,addition,aryl,boronic,acids,dienes,Various,substituted,both,parent,skeleton,phosphine,atoms,were,well,tolerated,this,method,provided,chiral,oxides,satisfied,yield,up,ee,corresponding,displayed,advantage,over,representative,Pd,reaction
AB值：
0.592185
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