典型文献
Na-MnOx catalyzed aerobic oxidative cleavage of biomass-derived 1,2-diols to synthesis medium-chain furanic chemicals
文献摘要：
Medium-chain furanic chemicals have outstanding practical potential,especially in the application of pharmaceuticals and polymers.Herein,we describe an eco-friendly and efficient heterogeneous sodium-doped porous sodium manganese oxide catalyst(Na-MnOx)for oxidative cleavage of furanic 1,2-diols into medium-chain furanic aldehyde compounds.Subsequently,various high value-added chemicals(diacids and esters,diols,hydroxy acids,acrylics)were synthesized based on the widely applicable and highly selective catalytic approaches.The Na-MnOx was prepared by the coprecipitation method and characterized by XRD,SEM,XPS and FT-IR,and TGA.XPS revealed that Mn species existed in the mixed oxidation states MnⅡ,MnⅢ and MnⅣ.When NaOH concentration up to 1.8 mol L-1 during the preparation process of the catalyst,the ratio of Mn4+in the catalyst was the highest,and the yield of product(Furan-2-acrolein)in the model reaction is also optimal.Overall,this protocol developed a novel and general route for the preparation of medium-chain furanic compounds utilizing cellulose-derived platform molecules.
文献关键词：
中图分类号：
作者姓名：
Qing-Shan Kong;Xing-Long Li;Hong-Bo Shen;Hua-Jian Xu;Yao Fu
作者机构：
Hefei National Laboratory for Physical Sciences at the Microscale,iChEM,CAS Key Laboratory of Urban Pollutant Conversion,Anhui Province Key Laboratory of Biomass Clean Energy,Institute of Energy,Hefei Comprehensive National Science Center Department of Chemistry,University of Science and Technology of China,Hefei,230026,China;School of Food and Biological Engineering,Hefei University of Technology,Hefei,230009,China;Institute of Energy,Hefei Comprehensive National Science Center Hefei,230031,China
文献出处：
引用格式：
[1]Qing-Shan Kong;Xing-Long Li;Hong-Bo Shen;Hua-Jian Xu;Yao Fu-.Na-MnOx catalyzed aerobic oxidative cleavage of biomass-derived 1,2-diols to synthesis medium-chain furanic chemicals)[J].绿色能源与环境（英文）,2022(05):957-964
A类：
furanic,diacids,acrylics,Mn4+in
B类：
MnOx,catalyzed,aerobic,oxidative,cleavage,biomass,derived,diols,synthesis,medium,chain,chemicals,Medium,have,outstanding,practical,potential,especially,application,pharmaceuticals,polymers,Herein,describe,eco,friendly,efficient,heterogeneous,sodium,doped,porous,manganese,oxide,catalyst,into,aldehyde,compounds,Subsequently,various,value,added,esters,hydroxy,were,synthesized,widely,applicable,highly,selective,catalytic,approaches,was,prepared,by,coprecipitation,method,characterized,XPS,FT,TGA,revealed,that,species,existed,mixed,oxidation,states,When,NaOH,concentration,up,during,preparation,process,highest,yield,product,Furan,acrolein,model,reaction,also,optimal,Overall,this,protocol,developed,novel,general,route,utilizing,cellulose,platform,molecules
AB值：
0.578633
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