典型文献
Photoinduced and palladium-catalyzed hydrogen atom transfer triggered 1,2-difunctionalization of 1,3-dienes with hydroxamides
文献摘要：
The discovery of novel catalysis modes to generate a significant increase in structural complexity from readily available reactants is a fundamental goal in modern organic synthesis.Here,we report a photoinduced palladium-catalyzed hydrogen atom transfer triggered 1,2-difunctionalization of conjugated dienes.Without the employment of exogeneous photosensitizers and external oxidants,the cascade reaction realized the integration of remote functionalization of various C(sp3)-H bonds and selective difunctionalization of 1,3-dienes with 100％atom efficiency,allowing for the synthesis of structurally diverse amides with up to 90％yields.Given the prevalence of amides in pharmaceuticals and natural products,the current protocol has provided an efficient means to access highly functionalized amides from readily available carboxylic acid derivatives and 1,3-dienes.
文献关键词：
中图分类号：
作者姓名：
Xiao-Yun Ruan;Tao Zhang;Wen-Ao Li;Yi-Zhuo Yin;Zhi-Yong Han;Liu-Zhu Gong
作者机构：
Department of Chemistry,University of Science and Technology of China,Hefei 230026,China
文献出处：
引用格式：
[1]Xiao-Yun Ruan;Tao Zhang;Wen-Ao Li;Yi-Zhuo Yin;Zhi-Yong Han;Liu-Zhu Gong-.Photoinduced and palladium-catalyzed hydrogen atom transfer triggered 1,2-difunctionalization of 1,3-dienes with hydroxamides)[J].中国科学:化学（英文版）,2022(05):863-869
A类：
difunctionalization,hydroxamides,exogeneous
B类：
Photoinduced,palladium,catalyzed,hydrogen,atom,transfer,triggered,dienes,discovery,novel,catalysis,modes,generate,significant,increase,complexity,from,readily,available,reactants,fundamental,goal,modern,organic,synthesis,Here,we,report,photoinduced,conjugated,Without,employment,photosensitizers,external,oxidants,cascade,reaction,realized,integration,remote,various,sp3,bonds,selective,efficiency,allowing,structurally,diverse,up,yields,Given,prevalence,pharmaceuticals,natural,products,current,protocol,has,provided,efficient,means,access,highly,functionalized,carboxylic,acid,derivatives
AB值：
0.591025
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