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典型文献
Catalyst design strategy toward the efficient heterogeneously-catalyzed selective oxidation of 5-hydroxymethylfurfural
文献摘要:
The selective oxidation of 5-hydroxymethylfurfural(HMF),a versatile bio-based platform molecule,leads to the formation of several intriguing and useful downstream chemicals,such as 2,5-diformylfuran(DFF),5-hydroxymethyl-2-furancarboxylic acid(HMFCA),formyl 2-furancarboxylic acid(FFCA),2,5-furandicarboxylic acid(FDCA)and furan-2,5-dimethylcarboxylate(FDMC).These products have been extensively employed to fabricate novel polymers,pharmaceuticals,sustainable dyes and many other value-added fine chemicals.The heart of the developed HMF oxidation processes is always the catalyst.In this regard,this review comprehensively summarized the established het-erogeneous catalyst design strategy for the selective oxidation of HMF via thermo-catalysis.Particular attention has been focused on the reaction mechanism of HMF oxidation over different catalysts as well as enhancing the catalytic performance of the catalyst through manipulating the properties of the support and fabricating of multi-component metal nano-particles and oxides.The current challenges and possible research directions for the catalytic oxidation of HMF in the future are also discussed.
文献关键词:
作者姓名:
Huai Liu;Xing Tang;Xianhai Zeng;Yong Sun;Xixian Ke;Tianyuan Li;Jiaren Zhang;Lu Lin
作者机构:
BiomassChem Group,Faculty of Chemical Engineering,Kunming University of Science and Technology,Kunming,650500,China;Xiamen Key Laboratory of Clean and High-valued Utilization for Biomass,College of Energy,Xiamen University,Xiang'an South Road,Xiamen,361102,China;Fujian Engineering and Research Center of Clean and High-valued Technologies for Biomass,Xiamen University,Xiang'an South Road,Xiamen,361005,China;Key Lab for Sport Shoes Upper Materials of Fujian Province(Fujian Huafeng New Material Co.,Ltd.),Putian,351144,China;PetroChina Petrochemical Research Institute,Beijing,102206,China
引用格式:
[1]Huai Liu;Xing Tang;Xianhai Zeng;Yong Sun;Xixian Ke;Tianyuan Li;Jiaren Zhang;Lu Lin-.Catalyst design strategy toward the efficient heterogeneously-catalyzed selective oxidation of 5-hydroxymethylfurfural)[J].绿色能源与环境(英文),2022(05):900-932
A类:
diformylfuran,furancarboxylic,HMFCA,FFCA,furandicarboxylic,dimethylcarboxylate,FDMC
B类:
Catalyst,design,strategy,toward,efficient,heterogeneously,catalyzed,selective,oxidation,hydroxymethylfurfural,versatile,bio,platform,molecule,leads,formation,several,intriguing,useful,downstream,chemicals,such,DFF,acid,FDCA,These,products,have,been,extensively,employed,fabricate,novel,polymers,pharmaceuticals,sustainable,dyes,many,other,value,added,fine,heart,developed,processes,always,In,this,regard,review,comprehensively,summarized,established,via,thermo,catalysis,Particular,attention,has,focused,reaction,mechanism,over,different,catalysts,well,enhancing,catalytic,performance,through,manipulating,properties,support,fabricating,multi,component,metal,nano,particles,oxides,current,challenges,possible,research,directions,future,are,also,discussed
AB值:
0.558554
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Base-free oxidative esterification of 5-hydroxymethylfurfural to furan-2,5-dimethylcarboxylate over n-doped carbon-supported Co/Fe bimetallic catalyst under batch-operation or continuous-flow conditions
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