典型文献
Two at the price of one:kinetic resolution of multi-substituted metallocenes
文献摘要：
Molecules containing the key planar chiral scaffold are com-monly used as ligands in asymmetric catalysis[1].As such,devel-oping efficient methods to rapidly functionalize planar chiral scaffolds has received substantial attention,and several elegant synthetic strategies have been developed to this end.Over the past decade,transition-metal-catalyzed enantioselective C-H functionalization has become one of the most powerful strategies in the field[2].Previous works on the syntheses of planar chiral 1,2-disubstituted metallocenes often rely on the use of pre-installed chiral auxiliaries or stoichiometric amounts of chiral bases[3],but these methods are limited to preparation of 1,2-dis-ubstituted metallocenes and construction of C-N[4]and C-Si bonds[5].
文献关键词：
中图分类号：
作者姓名：
Yuanyuan Li;Zhenhua Gu
作者机构：
Department of Chemistry,University of Science and Technology of China,Hefei 230026,China
文献出处：
引用格式：
[1]Yuanyuan Li;Zhenhua Gu-.Two at the price of one:kinetic resolution of multi-substituted metallocenes)[J].科学通报（英文版）,2022(24):2502-2504
A类：
metallocenes,ubstituted
B类：
Two,price,one,kinetic,resolution,multi,Molecules,containing,key,planar,chiral,are,monly,used,ligands,asymmetric,catalysis,such,oping,efficient,methods,rapidly,functionalize,scaffolds,has,received,substantial,attention,several,elegant,synthetic,strategies,have,been,developed,this,end,Over,past,decade,transition,catalyzed,enantioselective,functionalization,become,most,powerful,field,Previous,works,syntheses,disubstituted,often,rely,installed,auxiliaries,stoichiometric,amounts,bases,but,limited,preparation,construction,Si,bonds
AB值：
0.621562
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
