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典型文献
The exquisite integration of ESIPT,PET and AIE for constructing fluorescent probe for Hg(Ⅱ)detection and poisoning
文献摘要:
Excessive mercury ions(Hg2+)in the environment can accumulate in human body along with the food chain to cause serious physiological reactions.The fluorescence probes were considered as conve-nient tool with great potential for Hg2+detection.Most existing probes suffer from aggregation-induced quenching(ACQ)effects and insufficient sensitivity.Herein,a novel type of fluorophore was developed by combining the aggregation-induced emission(AIE)and excited state intramolecular proton transfer(ES-IPT)characteristics.Subsequently,a phenyl thioformate group with photoinduced electron transfer(PET)effect was connected to give an efficient"turn-on"probe(HTM),which exhibited good selectivity toward Hg2+,short response time(30 min),coupled with extremely low detection limit(LOD=1.68 nmol/L).In addition,HTM was used successfully in real samples,cells and drug evaluation,underlying the superiority of HTM to detect Hg2+in practical applications.
文献关键词:
作者姓名:
Xiang Cheng;Shuai Huang;Qian Lei;Fei Chen;Fan Zheng;Shibo Zhong;Xueyan Huang;Bin Feng;Xueping Feng;Wenbin Zeng
作者机构:
Xiangya School of Pharmaceutical Sciences,Central South University,Changsha 410013,China;The Molecular Imaging Research Center,Central South University,Changsha 410013,China;Hunan Key Laboratory of Diagnostic and Therapeutic Drug Research for Chronic Diseases,Central South University,Changsha 410013,China;Xiangya Hospital,Central South University,Changsha 410013,China
引用格式:
[1]Xiang Cheng;Shuai Huang;Qian Lei;Fei Chen;Fan Zheng;Shibo Zhong;Xueyan Huang;Bin Feng;Xueping Feng;Wenbin Zeng-.The exquisite integration of ESIPT,PET and AIE for constructing fluorescent probe for Hg(Ⅱ)detection and poisoning)[J].中国化学快报(英文版),2022(04):1861-1864
A类:
Hg2+detection,thioformate,Hg2+in
B类:
exquisite,integration,ESIPT,PET,AIE,constructing,fluorescent,poisoning,Excessive,mercury,environment,can,accumulate,human,body,along,food,chain,cause,serious,physiological,reactions,fluorescence,probes,were,considered,conve,nient,tool,great,potential,Most,existing,suffer,from,aggregation,quenching,ACQ,effects,insufficient,sensitivity,Herein,novel,type,fluorophore,was,developed,by,combining,emission,excited,state,intramolecular,proton,transfer,characteristics,Subsequently,phenyl,group,photoinduced,electron,connected,give,efficient,turn,HTM,which,exhibited,good,selectivity,toward,short,response,coupled,extremely,low,limit,LOD,nmol,In,addition,used,successfully,real,samples,cells,drug,evaluation,underlying,superiority,practical,applications
AB值:
0.671622
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