Indium tin oxide(ITO)is widely used in transparent conductive films(TCFs);however,several disadvan-tages,such as high cost and toxicity of indium,limit its applications.Therefore,it is necessary to develop other materials that can replace ITO.Silver nanowires or single walled carbon nanotubes(SWCNTs)have attracted considerable interest owing to their unique electrical,optical,and thermal stabilities,and thus,they are ideal for transparent electrodes for flexible or stretchable devices.In this study,we develop a novel architecture of composite TCFs on a polyethylene naphthalate(PEN)flexible substrate.Herein,the silver nanowires-SWCNTs films with nested density structure were fabricated through ultrasonic spraying technology by varying the spraying width.For achieving enhanced transmittance,we combined the larger irregular grids and holes with fewer nanowires stacked in the longitudinal direction,more optical chan-nels,and good carrier transport.Thereafter,aluminum-doped zinc oxide(AZO)was used as capping to the structure for enhancing the optical properties of the TCFs.The silver nanowires-SWCNTs/AZO(ASA)bilayer was obtained in the optimized architecture,which showed superior optoelectronic performance to that shown by commercial ITO with a high optical transmittance of 92％at the wavelength of 550 nm and low sheet resistance of 17 Ω/sq.In the specially structured conductive film,the significant improvement in the transmittance and uniformity of the sheet resistance was attributed to the effective nanowire junc-tion contact compared to that in ordinary structure of silver nanowires,which reduced the mean density of small clusters of nanowires.Compared with the silver nanowires-SWCNTs films,the ASA bilayer film exhibited excellent resistance to boiling,mechanical bending(10,000 cycles),and CO2 plasma.Moreover,the sheet resistance of ASA changed slightly after the tape tests,thereby illustrating a strong adhesion to the PEN substrate after the enclosure of AZO.Meanwhile,the AZO capping layer can enhance the op-tical transmittance between 600 and 1500 nm.In addition,the amorphous silicon photovoltaic devices with flexible ASA TCFs exhibited a power conversion efficiency(PCE)of 8.67％.After bending for 3000 times,the PCE was decreased to 8.20％,thereby demonstrating the potential of developed films to replace traditional ITO.

Shunliang Gao;Xiaohui Zhao;Qi Fu;Tianchi Zhang;Jun Zhu;Fuhua Hou;Jian Ni;Chengjun Zhu;Tiantian Li;Yanlai Wang;Vignesh Murugadoss;Gaber A.M.Mersal;Mohamed M.Ibrahim;Zeinhom M.El-Bahy;Mina Huang;Zhanhu Guo

The Key Laboratory of Semiconductor Photovoltaic Technology at Universities of Inner Mongolia Autonomous Region,College of Physical Science and Technology,Inner Mongolia University,Hohhot 010021,China;Department of Electronic Science and Technology,School of Electronic Information and Optical Engineering,Nankai University,Tianjin 300350,China;Advanced Materials Division,Engineered Multifunctional Composites(EMC)Nanotech LLC,Knoxville,TN 37934,United States;Integrated Composites Laboratory(ICL),Department of Chemical and Bimolecular Engineering,University of Tennessee,Knoxville,TN 37996,United States;Department of Chemistry,College of Science,Taif University,P.O.Box 11099,Taif 21944,Saudi Arabia;Department of Chemistry,Faculty of Science,Al-Azhar University,Nasr City 11884,Cairo,Egypt;College of Materials Science and Engineering,Taiyuan University of Science and Technology,Taiyuan 030024,China

材料科学技术（英文版）

[1]Shunliang Gao;Xiaohui Zhao;Qi Fu;Tianchi Zhang;Jun Zhu;Fuhua Hou;Jian Ni;Chengjun Zhu;Tiantian Li;Yanlai Wang;Vignesh Murugadoss;Gaber A.M.Mersal;Mohamed M.Ibrahim;Zeinhom M.El-Bahy;Mina Huang;Zhanhu Guo-.Highly transmitted silver nanowires-SWCNTs conductive flexible film by nested density structure and aluminum-doped zinc oxide capping layer for flexible amorphous silicon solar cells)[J].材料科学技术（英文版）,2022(31):152-160

TCFs,naphthalate

Highly,transmitted,silver,nanowires,SWCNTs,conductive,flexible,nested,density,aluminum,doped,zinc,oxide,capping,amorphous,silicon,solar,cells,Indium,ITO,widely,used,transparent,films,however,several,disadvan,tages,such,high,cost,toxicity,indium,limit,its,applications,Therefore,necessary,other,materials,that,replace,Silver,single,walled,carbon,nanotubes,have,attracted,considerable,interest,owing,their,unique,electrical,optical,thermal,stabilities,thus,they,ideal,electrodes,stretchable,devices,this,study,novel,architecture,composite,polyethylene,PEN,substrate,Herein,were,fabricated,through,ultrasonic,spraying,technology,varying,width,For,achieving,enhanced,transmittance,combined,larger,irregular,grids,holes,fewer,stacked,longitudinal,direction,more,nels,good,carrier,transport,Thereafter,AZO,was,enhancing,properties,ASA,bilayer,obtained,optimized,which,showed,superior,optoelectronic,performance,shown,commercial,wavelength,low,sheet,resistance,sq,specially,structured,significant,improvement,uniformity,attributed,effective,junc,contact,compared,ordinary,reduced,mean,small,clusters,Compared,exhibited,excellent,boiling,mechanical,bending,cycles,plasma,Moreover,changed,slightly,tape,tests,thereby,illustrating,strong,adhesion,enclosure,Meanwhile,between,addition,photovoltaic,power,conversion,efficiency,PCE,After,times,decreased,demonstrating,potential,developed,traditional

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