典型文献
Copper-catalyzed asymmetric propargylic substitution of anthrones and propargylic esters
文献摘要：
Anthrones are key structural motifs in many natural products,bioactive compounds and pharmaceuti-cal chemicals.Earth-abundant-metal-catalyzed asymmetric functionalization of anthrones has not proved to be viable.Herein,we disclosed a highly enantioselective propargylic substitution of anthrones with propargylic esters using copper salts with chiral N,N,P-ligand.This strategy is amenable to a broad range of substrates,uses readily available starting materials,provides excellent yields with remarkable enantioselectivity under mild conditions,and enables attractive products diversification routes.
文献关键词：
中图分类号：
作者姓名：
Zhiheng Li;Danran Li;Huaming Xiang;Jian Huang;Yinuo Zheng;Cuiju Zhu;Xiuling Cui;Chao Pi;Hao Xu
作者机构：
Green Catalysis Center,and College of Chemistry,Henan Key Laboratory of Chemical Biology and Organic Chemistry,Key Laboratory of Applied Chemistry of Henan Universities,Zhengzhou University,Zhengzhou 450001,China;Key Laboratory of Pesticides&Chemical Biology Ministry of Education,College of Chemistry,Central China Normal University,Wuhan 430079,China
文献出处：
引用格式：
[1]Zhiheng Li;Danran Li;Huaming Xiang;Jian Huang;Yinuo Zheng;Cuiju Zhu;Xiuling Cui;Chao Pi;Hao Xu-.Copper-catalyzed asymmetric propargylic substitution of anthrones and propargylic esters)[J].中国化学快报（英文版）,2022(02):867-870
A类：
propargylic,anthrones,Anthrones,pharmaceuti
B类：
Copper,catalyzed,asymmetric,substitution,esters,are,key,structural,motifs,many,natural,products,bioactive,compounds,chemicals,Earth,abundant,metal,functionalization,has,not,proved,be,viable,Herein,we,disclosed,highly,enantioselective,using,copper,salts,chiral,ligand,This,strategy,amenable,broad,range,substrates,uses,readily,available,starting,materials,provides,excellent,yields,remarkable,enantioselectivity,under,mild,conditions,enables,attractive,diversification,routes
AB值：
0.658416
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