典型文献
Palladium-catalyzed base-and solvent-controlled chemoselective allylation of amino acids with allylic carbonates
文献摘要：
The utilization of readily available amino acids,which is not only an oxygen nucleophile but also a nitrogen nucleophile,in palladium-catalyzed allylic substitution is realized under mild conditions.The chemoselectivity and multiple allylation are controlled by adjusting the reaction conditions.This repre-sents the first example of this convenient access to valuable N,O-diallylated amino acids.Under the title conditions,a range of amino acids(α-,β-,γ-)and dipeptides can be readily converted in to the corre-sponding allylic products with excellent yields(67 examples,up to 99％yield)as well as good functional group tolerance.
文献关键词：
中图分类号：
作者姓名：
Yang Zhou;Hang Chen;Panpan Lei;Chunming Gui;Haifeng Wang;Qiongjiao Yan;Wei Wang;Fener Chen
作者机构：
Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province,China West Normal University,Nanchong 637009,China;Pharmaceutical Research Institute,Wuhan Institute of Technology,Wuhan 430205,China;Engineering Center of Catalysis and Synthesis for Chiral Molecules,Department of Chemistry,Fudan University,Shanghai 200433,China;Shanghai Engineering Center of Industrial Catalysis for Chiral Drugs,Shanghai 200433,China
文献出处：
引用格式：
[1]Yang Zhou;Hang Chen;Panpan Lei;Chunming Gui;Haifeng Wang;Qiongjiao Yan;Wei Wang;Fener Chen-.Palladium-catalyzed base-and solvent-controlled chemoselective allylation of amino acids with allylic carbonates)[J].中国化学快报（英文版）,2022(11):4850-4855
A类：
nucleophile,diallylated
B类：
Palladium,catalyzed,base,solvent,controlled,chemoselective,allylation,amino,acids,allylic,carbonates,utilization,readily,available,which,not,only,oxygen,but,also,nitrogen,palladium,substitution,realized,under,mild,conditions,chemoselectivity,multiple,are,by,adjusting,reaction,This,repre,sents,first,this,convenient,access,valuable,Under,title,range,dipeptides,can,be,converted,corre,sponding,products,excellent,yields,examples,well,good,functional,group,tolerance
AB值：
0.623016
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
