典型文献
Altering elastic-plastic mechanical response of a series of isostructural metal-organic complex crystals
文献摘要：
The mechanically compliant single crystals have attracted massive attention.However,the related reports on the single crystals composed of metal-organic complexes remain scarce.In this study,we synthesized a series of isostructural single crystals of ZnⅡcomplexes that manifest mechanical bending in response to external stress.In these crystals,the mechanical responses can be shifted between elastic bending and plastic bending by the control of the intermolecular interactions through a rational structural modification in the substituent group of pyridine ligands.As the molecular reorientation corresponding to ligand variation elongates the interfacial distance between molecular slip planes,and the structural disorder of ligands disperses the interplanar intermolecular interactions,the shift from elastic bending to plastic bending of the metal-organic complex-based single crystal was realized.The different mechanical responses of single crystals were comprehensively investigated both experimentally and theoretically.
文献关键词：
中图分类号：
作者姓名：
Zheng Tang;Xiao-Peng Sun;Shu-Dong Wang;Xue-Yang Ji;Yun Li;Zi-Shuo Yao;Jun Tao
作者机构：
Key Laboratory of Cluster Science of Ministry of Education,School of Chemistry and Chemical Engineering,Beijing Institute of Technology,Beijing 100081,China;Henan Key Laboratory of Polyoxometalate Chemistry,College of Chemistry and Chemical Engineering,Henan University,Kaifeng 475004,China
文献出处：
引用格式：
[1]Zheng Tang;Xiao-Peng Sun;Shu-Dong Wang;Xue-Yang Ji;Yun Li;Zi-Shuo Yao;Jun Tao-.Altering elastic-plastic mechanical response of a series of isostructural metal-organic complex crystals)[J].中国科学:化学（英文版）,2022(04):710-718
A类：
elongates
B类：
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AB值：
0.525728
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