典型文献
Single molecule magnetic behavior and photo-enhanced proton conductivity in a series of photochromic complexes
文献摘要：
Molecules with multifunctional properties are of immense interest in hybrid materials,while challenges still existed because of the limited compatibility of multiple functionalities in a single system.In this work,a series of metal-organic complexes were synthesized and characterized under the assembly of electron donor phosphonate,electron acceptor polypyridine ligand and spin carrier rare earth ions.All the compounds exhibited remarkable and reversible responses with photochromism and photomodu-lated fluorescence,originated from photogenerated radicals via electron transfer from phosphonates to polypyridine ligands.For the Dy analog,slow magnetic relaxation was observed at cryogenic tempera-ture,indicating the single-molecule magnetic behavior.Furthermore,photogenerated radicals could en-hance the proton conductive behavior,with about 2 times larger in magnitude after light irradiation for Dy and Y compounds.The introduction of photoluminescence,magnetism and proton conduction into metallic phosphonates can provide potential applications for photochromic materials.
文献关键词：
中图分类号：
作者姓名：
Qian Zhang;Jixiang Hu;Qi Li;Dongxue Feng;Zhenni Gao;Guoming Wang
作者机构：
College of Chemistry and Chemical Engineering,Qingdao University,Qingdao 266071,China
文献出处：
引用格式：
[1]Qian Zhang;Jixiang Hu;Qi Li;Dongxue Feng;Zhenni Gao;Guoming Wang-.Single molecule magnetic behavior and photo-enhanced proton conductivity in a series of photochromic complexes)[J].中国化学快报（英文版）,2022(03):1417-1421
A类：
polypyridine,photomodu,phosphonates
B类：
Single,molecule,magnetic,behavior,enhanced,proton,conductivity,series,photochromic,complexes,Molecules,multifunctional,properties,immense,interest,hybrid,materials,while,challenges,still,existed,because,limited,compatibility,multiple,functionalities,single,system,In,this,work,organic,were,synthesized,characterized,under,assembly,electron,donor,acceptor,spin,carrier,rare,earth,All,compounds,exhibited,remarkable,reversible,responses,photochromism,lated,fluorescence,originated,from,photogenerated,radicals,via,transfer,ligands,For,Dy,analog,slow,relaxation,was,observed,cryogenic,tempera,ture,indicating,Furthermore,could,conductive,about,times,larger,magnitude,after,light,irradiation,introduction,photoluminescence,magnetism,conduction,into,metallic,can,provide,potential,applications
AB值：
0.637828
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