典型文献
Spatiotemporally-regulated multienzymatic polymerization endows hydrogel continuous gradient and spontaneous actuation
文献摘要：
There are several natural materials which have evolved functional gradients,ingeniously attaining maximal efficacy from limited components.Herein,we utilized the spatiotemporal distribution of initiator acetylacetone to regulate the multienzyme poly-merization and fabricate a chitosan-polymer hydrogel.The temporal priority order of acetylacetone was higher than phenol-modified chitosan by density functional theory calculation.The acetylacetone within the gelatin could gradually diffuse spatially into the chitosan hydrogel to fabricate the composite hydrogel with gradient network structure.The gradient hydrogel possessed a transferring topography from the two-dimensional pattem.A continuously decreased modulus along with acetylacetone diffusion was confirmed by atomic force microscope-based force mapping experiment.The water-retaining ability of various regions was confirmed by low-field nuclear magnetic resonance (NMR) and thermogravimetric analysis (TG) analysis,which led to the spontaneous actuation of gradient hydrogel with maximum 1821°/h curling speed and 227° curling angle.Conse-quently,the promising gradient hydrogels could be applied as intelligent actuators and flexible robots.
文献关键词：
中图分类号：
作者姓名：
Saiji Shen;Chu Wu;Yinghui Shang;Hongdou Shen;Yue Liao;Yuting Guo;Min Hu;Xia Wang;Gang Li;Qigang Wang
作者机构：
School of Chemical Science and Engineering,Tongji University,Shanghai 200092,China;College of Electronics and Information Engineering,Tongji University,Shanghai 201804,China
文献出处：
引用格式：
[1]Saiji Shen;Chu Wu;Yinghui Shang;Hongdou Shen;Yue Liao;Yuting Guo;Min Hu;Xia Wang;Gang Li;Qigang Wang-.Spatiotemporally-regulated multienzymatic polymerization endows hydrogel continuous gradient and spontaneous actuation)[J].中国科学:化学（英文版）,2022(01):153-161
A类：
Spatiotemporally,multienzymatic,multienzyme,pattem
B类：
regulated,polymerization,endows,spontaneous,actuation,There,are,several,natural,materials,which,have,evolved,functional,gradients,ingeniously,attaining,maximal,efficacy,from,limited,components,Herein,we,utilized,spatiotemporal,distribution,initiator,acetylacetone,fabricate,chitosan,priority,order,was,higher,than,phenol,modified,by,density,theory,calculation,within,gelatin,could,gradually,diffuse,spatially,into,composite,network,structure,possessed,transferring,topography,dimensional,continuously,decreased,modulus,along,diffusion,confirmed,atomic,force,microscope,mapping,experiment,water,retaining,ability,various,regions,low,field,nuclear,magnetic,resonance,NMR,thermogravimetric,analysis,led,maximum,curling,speed,angle,Conse,quently,promising,hydrogels,be,applied,intelligent,actuators,flexible,robots
AB值：
0.601645
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
