典型文献
Sn nanoparticles embedded into porous hydrogel-derived pyrolytic carbon as composite anode materials for lithium-ion batteries
文献摘要:
The composite powders,Sn nanoparticles embedded into the porous hydrogel-derived carbon(Sn@PHDC),were successfully prepared by polymerization and calcination processes,and the characterization results confirmed that Sn nanoparticles were homogeneously dis-persed in the porous hydrogel-derived pyrolytic carbon.The coin cell assembled with the Sn@PHDC-50 composite electrode presented good cyclic stability and rate perfor-mance when the weight ratio of Sn nanoparticles to hydro-gel-derived pyrolytic carbon was maintained at 1∶1.Moreover,the Sn@PHDC-50 electrode manifested a lower charge transfer resistance of 58.57 Ω and a higher lithium ions diffusion coefficient of 1.117×10-14 cm2·s-1 than pure Sn and other Sn@PHDC electrodes.Those improve-ments can be partly ascribed to the fact that the hydrogel-derived pyrolytic carbon matrix can release the volume strain and enhance the electronic conductivity of the composite electrode,and partly to the fact that the porous hydrogel-derived pyrolytic carbon matrix can suppress agglomera-tions of Sn nanoparticles and shorten Li+diffusion paths.This work may provide a new approach for the improvement of Sn-based anode materials for lithium-ion batteries.
文献关键词:
中图分类号:
作者姓名:
Guan-Li Xu;Yu-Dong Gong;Chang Miao;Qing Wang;Shu-Qing Nie;Yu Xin;Min-Yue Wen;Jian Liu;Wei Xiao
作者机构:
College of Chemistry and Environmental Engineering,Yangtze University,Jingzhou 434023,China;Hebei Key Laboratory of Dielectric and Electrolyte Functional Material,Northeastern University at Qinhuangdao,Qinhuangdao 066004,China;Peking University Science Park,Beijing 100871,China;School of Engineering,Faculty of Applied Science,The University of British Columbia,Kelowna,BC V1V 1V7,Canada
文献出处:
引用格式:
[1]Guan-Li Xu;Yu-Dong Gong;Chang Miao;Qing Wang;Shu-Qing Nie;Yu Xin;Min-Yue Wen;Jian Liu;Wei Xiao-.Sn nanoparticles embedded into porous hydrogel-derived pyrolytic carbon as composite anode materials for lithium-ion batteries)[J].稀有金属(英文版),2022(10):3421-3431
A类:
PHDC,agglomera
B类:
Sn,nanoparticles,embedded,into,porous,hydrogel,derived,pyrolytic,carbon,composite,anode,materials,lithium,batteries,powders,were,successfully,prepared,by,polymerization,calcination,processes,characterization,results,confirmed,that,homogeneously,dis,persed,coin,cell,assembled,presented,good,cyclic,stability,rate,perfor,mance,when,weight,ratio,was,maintained,Moreover,manifested,lower,charge,transfer,resistance,higher,coefficient,than,pure,other,electrodes,Those,ments,can,partly,ascribed,fact,matrix,release,volume,strain,enhance,electronic,conductivity,suppress,tions,shorten,Li+diffusion,paths,This,work,may,provide,new,approach,improvement
AB值:
0.46835
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