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典型文献
Optimizing side chains on different nitrogen aromatic rings achieving 17% efficiency for organic photovoltaics
文献摘要:
Balancing charge generation and low energy loss (Eloss),especially in the wide spectral absorption region is critical to obtain high-performance organic photovoltaics (OPVs).Therefore,Y11-M and Y11-EB are designed and synthesized through modifying alkyl chains on different nitrogen aromatic rings of the reported non-fullerene acceptor Y11.Although all the molecules have almost similar low band-gap(around 1.30 eV),Y11-M and Y11-EB exhibit wider absorption in 410-870 nm region.Eventually,the conventional devices based on Y11-M and Y11-EB possess more efficient charge generation with low Eloss (around 0.44 eV),In addition,outstanding efficiencies of 16,64% and 17,15% with the fill factor of 76.15% and 74.73% are obtained in PM6:Y11-M and PM6:Y11-EB-based devices,both higher than Y11:PM6.The results highlight the importance of rational alkyl chains optimization,and a good structure-property relationship is established as well.
文献关键词:
作者姓名:
Zhe Li;Can Zhu;Jun Yuan;Liuyang Zhou;Wei Liu;Xinxin Xia;Juan Hong;Honggang Chen;Qingya Wei;Xinhui Lu;Yongfang Li;Yingping Zou
作者机构:
College of Chemistry and Chemical Engineering,Central South University,Changsha 410000,Hunan,China;CAS Key Laboratory of Organic Solids,Institute of Chemistry Chinese Academy of Sciences,Beijing 100000,China;Department of Physics,The Chinese University of Hong Kong,Hong Kong 999077,China
文献出处:
引用格式:
[1]Zhe Li;Can Zhu;Jun Yuan;Liuyang Zhou;Wei Liu;Xinxin Xia;Juan Hong;Honggang Chen;Qingya Wei;Xinhui Lu;Yongfang Li;Yingping Zou-.Optimizing side chains on different nitrogen aromatic rings achieving 17% efficiency for organic photovoltaics)[J].能源化学,2022(02):173-178
A类:
B类:
Optimizing,side,chains,different,nitrogen,aromatic,rings,achieving,efficiency,organic,photovoltaics,Balancing,charge,generation,low,energy,Eloss,especially,spectral,absorption,region,critical,performance,OPVs,Therefore,Y11,EB,are,designed,synthesized,through,modifying,alkyl,reported,fullerene,acceptor,Although,molecules,have,almost,similar,band,gap,around,eV,exhibit,wider,Eventually,conventional,devices,possess,more,efficient,In,addition,outstanding,efficiencies,fill,obtained,PM6,both,higher,than,results,highlight,importance,rational,optimization,good,structure,property,relationship,established,well
AB值:
0.538496
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