典型文献
Planet-satellite cage hybrids:covalent organic cages encircling metal organic cage
文献摘要：
As a rising type of precisely molecular nanoobjects,porous molecular cages,including covalent organic cages(COCs)and metal organic cages(MOCs),have attracted much more attention.It is fascinating to construct well-defined cage hybrids combining COCs and MOCs to further rich their types,properties,and applications.However,it is a big challenge due to the isotropy of the porous molecular cages.In this article,an anisotropic COC ligand based on aryl ether bonds and bearing one isophthalate moiety has been designed and synthesized.Then planet-satellite cage hybrids(PSCHs),MOC@COCs,have been constructed through the coordination of the anisotropic COC ligand and copper ions with or without the help of extra dicarboxylic ligands in an almost quantitative manner for the first time.Three PSCHs with one different topological MOC(heteroleptic bipolar,distorted cuboctahedral or homoleptic cuboctahedral)as the planet and different numbers of COCs(6,12 or 24)as satellites are obtained.The structural and thermal properties of these PSCHs have also been studied.The obtained PSCHs exhibit discrete,uniform and stable structures,good solubility and strong film-forming property.
文献关键词：
中图分类号：
作者姓名：
Chenjuan Yu;Pan Yang;Xinyuan Zhu;Youfui Wang
作者机构：
School of Chemistry and Chemical Engineering,Frontiers Science Center for Transformative Molecules,Shanghai Jiao Tong University,Shanghai 200240,China;School of Materials Engineering,Shanghai University of Engineering Science,Shanghai 201620,China
文献出处：
引用格式：
[1]Chenjuan Yu;Pan Yang;Xinyuan Zhu;Youfui Wang-.Planet-satellite cage hybrids:covalent organic cages encircling metal organic cage)[J].中国科学:化学（英文版）,2022(05):858-862
A类：
nanoobjects,isophthalate,PSCHs,heteroleptic,cuboctahedral,homoleptic
B类：
Planet,hybrids,covalent,organic,cages,encircling,metal,rising,precisely,molecular,porous,including,COCs,MOCs,have,attracted,much,more,attention,It,fascinating,well,defined,combining,further,rich,their,types,properties,applications,However,big,challenge,due,isotropy,In,this,article,anisotropic,aryl,ether,bonds,bearing,one,moiety,has,been,designed,synthesized,Then,planet,constructed,through,coordination,copper,without,help,extra,dicarboxylic,ligands,almost,quantitative,manner,first,Three,different,topological,bipolar,distorted,numbers,satellites,are,obtained,structural,thermal,these,also,studied,exhibit,discrete,uniform,stable,structures,good,solubility,strong,film,forming,property
AB值：
0.493942
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