Despite the significant progress made recently in all-polymer solar cells(all-PSCs),it is still quite challenging to achieve high open-circuit voltage(Voc)and short-circuit current density(Jsc)simultaneously in order to further improve their performance.The recent strategy of using selenophene to replace thiophene on the Y6 based polymer acceptors has resulted in significantly improved Jscs of the resulting all-PSCs.However,such modifications have also depressed Voc,which compromises the overall performance of the devices.Herein,we present the design and synthesis of a novel polymer acceptor,PYT-1S1Se,created by inserting an asymmetrical selenophene-fused framework to precisely manipulate optical absorption and electronic properties.Compared with the selenium-free analog,PYT-2S,and symmetrical selenium-fused analog,PYT-2Se,the PYT-1S1Se derived all-PSCs not only deliver optimized Jsc(24.1 mA cm-2)and Voc(0.926 V)metrics,but also exhibit a relatively low energy loss of 0.502 eV.Consequently,these devices obtain a record-high power conversion efficiency(PCE)of 16.3％in binary all-PSCs.This work demonstrates an effective molecular design strategy for balancing the trade-off betweenVocand Jsc to achieve high-efficiency all-PSCs.

Huiting Fu;Qunping Fan;Wei Gao;Jiyeon Oh;Yuxiang Li;Francis Lin;Feng Qi;Changduk Yang;Tobin J.Marks;Alex K.-Y.Jen

Department of Materials Science and Engineering,City University of Hong Kong,Kowloon 999077,Hong Kong,China;Department of Chemistry,City University of Hong Kong,Kowloon 999077,Hong Kong,China;Institute for Advanced Studies,City University of Hong Kong,Kowloon 999077,Hong Kong,China;Department of Energy Engineering,School of Energy and Chemical Engineering,Perovtronics Research Center Low Dimensional Carbon Materials Center Ulsan National Institute of Science and Technology(UNIST),50 UNIST-gil,Ulju-gun,Ulsan 44919,Republic of Korea;Department of Chemistry and the Materials Research Center Northwestern University,Evanston,IL,60208,USA;Department of Materials Science and Engineering,University of Washington,Seattle,Washington 98195-2120,USA

中国科学:化学（英文版）

[1]Huiting Fu;Qunping Fan;Wei Gao;Jiyeon Oh;Yuxiang Li;Francis Lin;Feng Qi;Changduk Yang;Tobin J.Marks;Alex K.-Y.Jen-.16.3％Efficiency binary all-polymer solar cells enabled by a novel polymer acceptor with an asymmetrical selenophene-fused backbone)[J].中国科学:化学（英文版）,2022(02):309-317

selenophene,Jscs,PYT,1S1Se,2Se,betweenVocand

Efficiency,binary,polymer,solar,cells,enabled,by,novel,asymmetrical,fused,backbone,Despite,progress,made,recently,PSCs,still,quite,challenging,achieve,high,open,circuit,voltage,short,current,density,simultaneously,order,further,their,performance,strategy,using,replace,thiophene,Y6,acceptors,has,resulted,significantly,improved,resulting,However,such,modifications,have,also,depressed,which,compromises,overall,devices,Herein,present,design,synthesis,created,inserting,framework,precisely,manipulate,optical,absorption,electronic,properties,Compared,selenium,free,analog,derived,not,only,deliver,optimized,mA,metrics,but,exhibit,relatively,low,energy,loss,eV,Consequently,these,obtain,record,power,conversion,efficiency,PCE,This,demonstrates,effective,molecular,balancing,trade,off

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