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典型文献
Recent advances in gold-complex and chiral organocatalyst cooperative catalysis for asymmetric alkyne functionalization
文献摘要:
Homogeneous gold catalysis has demonstrated the preponderant capability of realizing a broad range of synthetically versatile alkyne functionalization over the last two decades.Though catalytic asymmetric alkyne transformation has focused on the principle of using gold catalysts either associated with chi-ral phosphine ligand or combined with chiral counterion,a variety of breakthroughs have been reported with the application of gold-complex and chiral organocatalyst cooperative catalysis strategy,which could enable the challenging transformations that cannot be realized by mono-catalysis with excellent stereos-electivity.This review will cover two general protocols in this field,including relay catalysis and synergis-tic catalysis,with emphasis on the detailed cooperative catalysts models to illustrate the roles of the two catalysts and highlight the potential synthetic opportunities offered by asymmetric cooperative catalysis.
文献关键词:
作者姓名:
Ming Bao;Su Zhou;Wenhao Hu;Xinfang Xu
作者机构:
Guangdong Key Laboratory of Chiral Molecule and Drug Discovery,School of Pharmaceutical Sciences,Sun Yat-sen University,Guangzhou 510006,China
引用格式:
[1]Ming Bao;Su Zhou;Wenhao Hu;Xinfang Xu-.Recent advances in gold-complex and chiral organocatalyst cooperative catalysis for asymmetric alkyne functionalization)[J].中国化学快报(英文版),2022(12):4969-4979
A类:
organocatalyst,preponderant,counterion,stereos,electivity
B类:
Recent,advances,gold,complex,chiral,cooperative,catalysis,asymmetric,alkyne,functionalization,Homogeneous,demonstrated,capability,realizing,broad,range,synthetically,versatile,last,two,decades,Though,catalytic,focused,principle,using,catalysts,either,associated,phosphine,ligand,combined,variety,breakthroughs,have,been,reported,application,strategy,which,could,enable,challenging,transformations,that,cannot,realized,by,mono,excellent,This,review,will,cover,general,protocols,this,field,including,relay,synergis,emphasis,detailed,models,illustrate,roles,highlight,potential,opportunities,offered
AB值:
0.526345
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