典型文献
Chiral pillar[n]arenes:Conformation inversion,material preparation and applications
文献摘要:
Chiral pillar[n]arenes have shown great research value and application prospect in construction of chi-ral materials and chiral applications,due to their inherent planar chiral configurations,chiral recognition ability,easy modification and highly symmetric hydrophobic cavity.This review systematically summa-rized the conformation inversion factors of planar chiral pillar[5]arenes(pR/pS),such as solvents,temper-ature,substituent size,alkyl chains,chiral and achiral guest molecules.We firstly introduced the applica-tions of chiral pillar[n]arenes for constructing chiral materials and pointed out that planar conformation inversion showed a great potential role in constructing chiral materials.Then,we mainly concluded the chiral applications of chiral and planar chiral pillar[n]arenes like chiral enantiomer analysis by circular dichroism,electrochemistry or chiral fluorescence sensing.From this review,we found that the inherent planar chiral conformation of chiral pillar[n]arenes have played a very important role in chiral field in the future.
文献关键词:
中图分类号:
作者姓名:
Chengxiang Shi;Hui Li;Xiaofeng Shi;Liang Zhao;Hongdeng Qiu
作者机构:
CAS Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,China;University of Chinese Academy of Sciences.Beijing 100049,China;Department of Gansu Provincial Cancer Hospital,Institute of Materia Medica,Lanzhou 730000,China;College of Chemistry,Zhengzhou University,Zhengzhou 450001,China;College of Chemistry and Chemical Engineering,Gannan Normal University,Ganzhou 341000,China
文献出处:
引用格式:
[1]Chengxiang Shi;Hui Li;Xiaofeng Shi;Liang Zhao;Hongdeng Qiu-.Chiral pillar[n]arenes:Conformation inversion,material preparation and applications)[J].中国化学快报(英文版),2022(08):3613-3622
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Chiral,pillar,arenes,Conformation,inversion,preparation,applications,have,shown,great,research,value,prospect,construction,materials,due,their,inherent,planar,configurations,recognition,ability,easy,modification,highly,symmetric,hydrophobic,cavity,This,review,systematically,summa,rized,conformation,factors,pR,pS,such,solvents,temper,ature,substituent,size,alkyl,chains,achiral,guest,molecules,We,firstly,introduced,constructing,pointed,out,that,showed,potential,role,Then,mainly,concluded,like,enantiomer,analysis,by,circular,dichroism,electrochemistry,fluorescence,sensing,From,this,found,played,very,important,field,future
AB值:
0.515225
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