典型文献
C-F bond functionalizations of trifluoromethyl groups via radical intermediates
文献摘要：
Selective functionalization of C-F bonds in trifluoromethyl groups has recently received a growing inter-est,as it offers atom-and step-economic pathways to access highly valuable mono-and difluoroalkyl-substituted organic molecules using simple and inexpensive trifluoromethyl sources as the starting mate-rials.In this regard,impressive progress has been made on the defluorinative functionalization reactions that proceed via radical intermediates.Nevertheless,it is still a great challenge to precisely control the defluorination process,due to the continuous decrease of the C-F bond strength after the replacement of one or two fluorine atoms with various functionalities.This review article is aimed to provide a brief overview of recently reported methods used to functionalize C-F bonds of CF3 groups via radical inter-mediates.An emphasis is placed on the discussion of mechanistic aspects and synthetic applications
文献关键词：
中图分类号：
作者姓名：
Tesfaye Tebeka Simur;Tian Ye;You-Jie Yu;Feng-Lian Zhang;Yi-Feng Wang
作者机构：
Department of Chemistry,University of Science and Technology of China,Hefei 230026,China
文献出处：
引用格式：
[1]Tesfaye Tebeka Simur;Tian Ye;You-Jie Yu;Feng-Lian Zhang;Yi-Feng Wang-.C-F bond functionalizations of trifluoromethyl groups via radical intermediates)[J].中国化学快报（英文版）,2022(03):1193-1198
A类：
functionalizations,difluoroalkyl
B类：
trifluoromethyl,groups,via,radical,intermediates,Selective,bonds,recently,received,growing,est,offers,step,economic,pathways,access,highly,valuable,mono,substituted,organic,molecules,using,simple,inexpensive,sources,starting,mate,rials,In,this,regard,impressive,progress,been,made,defluorinative,reactions,that,proceed,Nevertheless,still,great,challenge,precisely,control,defluorination,process,due,continuous,decrease,strength,after,replacement,one,two,fluorine,atoms,various,functionalities,This,review,article,aimed,provide,brief,overview,reported,methods,used,functionalize,CF3,An,emphasis,placed,discussion,mechanistic,aspects,synthetic,applications
AB值：
0.647858
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