典型文献
Anionic alkene-azide cycloaddition(AAAC)strategy toward electrosynthesis of multifunctionalized[60]fullerene derivatives and further applications
文献摘要：
It is a challenging task to control regioselective cycloaddition for polyolefins.Triazolines are a prominent class of heterocycles in organic synthesis and pharmaceutical chemistry.Among the numerous synthetic protocols for the formation of triazolines,the 1,3-dipolar cycloaddition of azides to neutral alkenes is an effective method[1].To the best of our knowledge,the ionic cycloaddition between azides and ionic alkenes remains unexplored to date.It has been found that C60 behaves like an electron-deficient alkene and that its[6,6]-bonds are C=C double bonds and dipolarophilic,which enable C60 to undergo various[2+3]cycloadditions[2].
文献关键词：
中图分类号：
作者姓名：
Xing-Xing Yan;Chuang Niu;Zheng-Chun Yin;Wen-Qiang Lu;Guan-Wu Wang
作者机构：
Hefei National Research Center for Physical Sciences at the Microscale and Department of Chemistry,University of Science and Technology of China,Hefei 230026,China;State Key Laboratory of Applied Organic Chemistry,Lanzhou University,Lanzhou 730000,China
文献出处：
引用格式：
[1]Xing-Xing Yan;Chuang Niu;Zheng-Chun Yin;Wen-Qiang Lu;Guan-Wu Wang-.Anionic alkene-azide cycloaddition(AAAC)strategy toward electrosynthesis of multifunctionalized[60]fullerene derivatives and further applications)[J].科学通报（英文版）,2022(23):2406-2410
A类：
multifunctionalized,polyolefins,Triazolines,triazolines,dipolarophilic
B类：
Anionic,AAAC,strategy,toward,electrosynthesis,fullerene,derivatives,further,applications,It,challenging,task,control,regioselective,are,prominent,class,heterocycles,organic,pharmaceutical,chemistry,Among,numerous,synthetic,protocols,formation,azides,neutral,alkenes,effective,method,To,best,our,knowledge,between,remains,unexplored,date,has,been,found,that,C60,behaves,like,electron,deficient,its,bonds,double,which,enable,undergo,various,2+3,cycloadditions
AB值：
0.562807
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