典型文献
Dinitrogen extrusion from diazene in organic synthesis
文献摘要：
Radical-mediated reactions have many advantages in the construction of complex molecular scaffolds by forging chemical bonds of high challenge.Diazenes,including 1,1-diazenes and 1,2-diazenes,can generate biradical species via nitrogen extrusion under thermal or photochemical conditions.The superior reactiv-ity of the generated biradical enables various types of synthetic transformations with excellent chemose-lectivity and has been applied to the complex natural products synthesis.In this mini-review,the modes of reaction are summarized and discussed,namely ring contraction via nitrogen deletion,homo or hetero-dimerization,trimethylenemethane(TMM)-diyl cycloaddition.Applications of these classes of reactions in complex natural product synthesis are illustrated.Last but not least,the current state,future directions,and opportunities for dinitrogen extrusion reaction from diazenes are highlighted and discussed.
文献关键词：
中图分类号：
作者姓名：
Chunngai Hui;Shiping Wang;Chunfa Xu
作者机构：
Institute of Pharmaceutical Science and Technology,College of Chemistry,Fuzhou University,Fuzhou 350108,China;Max Planck Institute of Molecular Physiology,Department of Chemical Biology,Dortmund 44227,Germany;National Engineering Research Center of Chemical Fertilizer Catalyst,College of Chemical Engineering,Fuzhou University,Fuzhou 350108,China
文献出处：
引用格式：
[1]Chunngai Hui;Shiping Wang;Chunfa Xu-.Dinitrogen extrusion from diazene in organic synthesis)[J].中国化学快报（英文版）,2022(08):3695-3700
A类：
diazene,Diazenes,diazenes,biradical,chemose,trimethylenemethane
B类：
Dinitrogen,extrusion,from,organic,synthesis,Radical,mediated,reactions,have,many,advantages,construction,complex,molecular,scaffolds,by,forging,bonds,challenge,including,can,species,via,under,thermal,photochemical,conditions,superior,reactiv,generated,enables,various,types,synthetic,transformations,excellent,lectivity,has,been,applied,natural,products,In,this,mini,review,modes,are,summarized,discussed,namely,ring,contraction,deletion,homo,hetero,dimerization,TMM,diyl,cycloaddition,Applications,these,classes,illustrated,Last,but,not,least,current,state,future,directions,opportunities,dinitrogen,highlighted
AB值：
0.61248
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