典型文献
Sustainable synthesis of high-density fuel via catalytic cascade cycloaddition reaction
文献摘要：
The access to high-density hydrocarbon fuels from biomass for the reduction of dependence on fossil resources has been a research highlight in recent years.It is well known that cycloalkanes are the com-ponents of fuels with higher energy density than straight or branched alkanes.Herein,we developed a new catalytic pattern to synthesize dimethyltetradecahydroanthracenes(DMTHA),a kind of tricyclic alkane,from biomass-derived isoprene and p-benzoquinone via a cascade Diels-Alder reaction followed by a hydrodeoxygenation reaction.Vanadium supported on titanium dioxide(V-TiO2)was applied to cat-alyze the cascade Diels-Alder reaction and it was disclosed that V with appropriate V4+/V5+ratio on the surface of TiO2 could activate quinones.Experimental tests showed that the heating value of final prod-ucts was up to 45.7 MJ/kg.The development of new high-density fuel molecules is a long-term trend for the future renewable and sustainable fuel energy application.
文献关键词：
中图分类号：
作者姓名：
Xiaolin Luo;Rui Lu;Xiaoqin Si;Huifang Jiang;Quan Shi;Haixia Ma;Cong Zhang;Jie Xu;Fang Lu
作者机构：
State Key Laboratory of Catalysis,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian National Laboratory for Clean Energy,Dalian 116023,Liaoning,China;University of Chinese Academy of Sciences,Beijing 100049,China;School of Chemical Engineering,Xi'an Key Laboratory of Special Energy Materials Northwest University,Xi'an 710069,Shaanxi,China
文献出处：
引用格式：
[1]Xiaolin Luo;Rui Lu;Xiaoqin Si;Huifang Jiang;Quan Shi;Haixia Ma;Cong Zhang;Jie Xu;Fang Lu-.Sustainable synthesis of high-density fuel via catalytic cascade cycloaddition reaction)[J].能源化学,2022(06):231-236
A类：
cycloalkanes,dimethyltetradecahydroanthracenes,DMTHA,V5+ratio
B类：
Sustainable,synthesis,density,via,catalytic,cascade,cycloaddition,reaction,access,hydrocarbon,fuels,from,biomass,reduction,dependence,fossil,resources,has,been,research,highlight,recent,years,It,well,known,that,are,com,ponents,higher,energy,than,straight,branched,Herein,developed,pattern,synthesize,kind,tricyclic,derived,isoprene,benzoquinone,Diels,Alder,followed,by,hydrodeoxygenation,Vanadium,supported,titanium,dioxide,TiO2,was,applied,alyze,disclosed,appropriate,V4+,surface,could,activate,quinones,Experimental,tests,showed,heating,value,final,prod,ucts,MJ,development,molecules,long,term,trend,future,renewable,sustainable,application
AB值：
0.605235
相似文献
机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
