典型文献
Advances in cycloaddition and hydroaddition reaction ofα-(trifluoromethyl)styrenes without defluorination:An alternative approach to CF3-containing compounds
文献摘要：
α-(Trifluoromethyl)styrene and its derivatives have found wide applications in the fields of pharmaceuti-cals,agrochemicals,and advanced materials.They are also versatile trifluoromethyl-containing building blocks for the preparation of various trifluoromethyl-containing,fluorine-containing or nonfluorinated compounds.Recently,great efforts have been made to develop diverse reactions for rapidly accessing a wide range of valuable gem-difluoroalkenes and gem-difluoroalkylated compounds via defluorinative re-action or the defluorinative ipso-functionalization reaction of α-(trifluoromethyl)styrenes,respectively.In contrast,α-(trifluoromethyl)styrenes remain notably underdeveloped with respect to their use in cycload-dition and hydroaddition reaction with retaining of three C-F bonds.This short review herein is aimed to summarize the recent progress on the cycloaddition and hydroaddition reaction including nucleophilic,radical and transition metal-catalyzed addition of α-(trifluoromethyl)styrenes without accompanying de-fluorination.
文献关键词：
中图分类号：
作者姓名：
Yupian Deng;Jingjing He;Song Cao;Xuhong Qian
作者机构：
Shanghai Key Laboratory of Chemical Biology,School of Pharmacy,East China University of Science and Technology(ECUST),Shanghai 200237,China;School of Chemistry and Molecular Engineering,East China Normal University,Shanghai 200062,China
文献出处：
引用格式：
[1]Yupian Deng;Jingjing He;Song Cao;Xuhong Qian-.Advances in cycloaddition and hydroaddition reaction ofα-(trifluoromethyl)styrenes without defluorination:An alternative approach to CF3-containing compounds)[J].中国化学快报（英文版）,2022(05):2363-2371
A类：
hydroaddition,styrenes,Trifluoromethyl,pharmaceuti,nonfluorinated,difluoroalkylated,cycload
B类：
Advances,cycloaddition,trifluoromethyl,without,defluorination,An,alternative,approach,CF3,containing,compounds,its,derivatives,have,found,wide,applications,fields,agrochemicals,advanced,materials,They,are,also,versatile,building,blocks,preparation,various,fluorine,Recently,great,efforts,been,made,diverse,reactions,rapidly,accessing,range,valuable,gem,difluoroalkenes,via,defluorinative,ipso,functionalization,respectively,In,contrast,remain,notably,underdeveloped,their,use,retaining,three,bonds,This,short,review,herein,aimed,summarize,recent,progress,including,nucleophilic,radical,transition,metal,catalyzed,accompanying
AB值：
0.510959
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