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典型文献
Dual-ionic imidazolium salts to promote synthesis of cyclic carbonates at atmospheric pressure
文献摘要:
Novel dual-ionic imidazolium salts are shown to display excellent catalytic activity for cycloaddition of carbon dioxide and epoxides under room temperature and atmospheric pressure(0.1 MPa)without any solvent and co-catalyst leading to 96.1%product yield.It can be reused five times to keep the product yield over 90%.These intriguing results are attributed to a new reaction mechanism,which is supported by theoretical calculations along with the measurements of 13C NMR spectrum and Fourier transform infrared spectroscopy(FT-IR).The excellent catalytic activity can be traced to a CO2-philic group along with an electrophilic hydrogen atom.Our work shows that incorporation of CO2-philic group is an feasible pathway to develop the new efficient ionic liquids.
文献关键词:
作者姓名:
Tengfei Wang;Danning Zheng;Beibei An;Yi Liu;Tiegang Ren;Hans ?gren;Li Wang;Jinglai Zhang;M?rten S.G.Ahlquist
作者机构:
Henan Engineering Research Center of Green Anticorrosion Technology for Magnesium Alloys,Henan University,Kaifeng,Henan,475004,China;Henan Engineering Research Center of Corrosion and Protection for Magnesium Alloys,Henan University,Kaifeng,Henan,475004,China;College of Chemistry and Chemical Engineering,Henan University,Kaifeng,Henan,475004,China;Department of Theoretical Chemistry&Biology,School of Biotechnology,KTH Royal Institute of Technology,10691 Stockholm,Sweden
引用格式:
[1]Tengfei Wang;Danning Zheng;Beibei An;Yi Liu;Tiegang Ren;Hans ?gren;Li Wang;Jinglai Zhang;M?rten S.G.Ahlquist-.Dual-ionic imidazolium salts to promote synthesis of cyclic carbonates at atmospheric pressure)[J].绿色能源与环境(英文),2022(06):1327-1339
A类:
B类:
Dual,ionic,imidazolium,salts,promote,synthesis,cyclic,carbonates,atmospheric,pressure,Novel,dual,shown,display,excellent,catalytic,activity,cycloaddition,dioxide,epoxides,under,room,temperature,without,any,solvent,catalyst,leading,product,yield,It,can,be,reused,five,times,keep,over,These,intriguing,results,attributed,new,reaction,mechanism,which,supported,by,theoretical,calculations,along,measurements,13C,NMR,spectrum,Fourier,transform,infrared,spectroscopy,FT,traced,group,electrophilic,hydrogen,atom,Our,work,shows,that,incorporation,feasible,pathway,develop,efficient,liquids
AB值:
0.664551
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