典型文献
A Novel 3D CdⅡ-Cp Based on a Bi-functional (N-/O-Sites)Triazole-modified Carboxyl Ligand:Structure,Topology and Photoluminescence
文献摘要：
With triazole-modified derivative as link,one new framework[Cd5(μ5-HL2-)2(μ4-L3-)2(H2O)10]·2H2O(1,H3L =2-(1,2,4-triazol-1-yl)benzene-l,3,5-tricarboxylic acid) has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction,powder X-ray diffraction and elemental analysis.Complex 1 exhibits a 3D (3,4,6)-connected net cross-linked by binuclear[Cd2(COO)5]-cluster and mononuclear Cd(Ⅱ)geometry via HL2-/L3-ligands.It crystallizes in triclinic system,space group P(-1) with a =7.7411(11),b =9.8813(15),c =20.177(3) (A),a =85.547(4)°,β =80.603(4)°,γ =67.976(3)°,V=1411.3(4) (A)3,Z =1,Mr =1876.89 g/mol,Dc =2.208 mg/m3,μ =1.97 mm-1,F(000) =918,GOOF =1.03,the final R =0.0869 and wR =0.1950 for 3127 observed reflections with Ⅰ ＞ 2σ(Ⅰ).The solid photoluminescent behaviour of 1 has been further functionally investigated.
文献关键词：
中图分类号：
作者姓名：
ZHAO Dan;GUO Ting-Ting;AN Yan-Yan;YAN Juan-Zhi
作者机构：
Taiyuan University,Taiyuan 030032,China
文献出处：
引用格式：
[1]ZHAO Dan;GUO Ting-Ting;AN Yan-Yan;YAN Juan-Zhi-.A Novel 3D CdⅡ-Cp Based on a Bi-functional (N-/O-Sites)Triazole-modified Carboxyl Ligand:Structure,Topology and Photoluminescence)[J].结构化学,2022(02):85-90
A类：
Triazole,GOOF
B类：
Novel,Cp,Based,Bi,Sites,modified,Carboxyl,Ligand,Structure,Topology,Photoluminescence,With,triazole,derivative,one,new,framework,Cd5,HL2,L3,2H2O,H3L,benzene,tricarboxylic,acid,has,been,hydrothermally,synthesized,characterized,by,single,ray,diffraction,powder,elemental,analysis,Complex,exhibits,connected,net,cross,linked,binuclear,Cd2,COO,cluster,mononuclear,geometry,via,ligands,It,crystallizes,triclinic,system,space,group,Mr,Dc,final,wR,observed,reflections,solid,photoluminescent,behaviour,further,functionally,investigated
AB值：
0.737452
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
