典型文献
Solid-state [2+2] Photocycloaddition Reaction of Zinc(Ⅱ)Complex Based on Quaternized 1,2-Bis(4'-pyridyl)ethylene
文献摘要：
A photoactive metal-organic complex[Zn2(BCbpe)2(p-DBC)2].5H2O(1) has been synthesized based on an olefin-containing pyridinium compound,1-(4-carboxybenzyl)-4-[2-(4-pyridyl)-vinyl]pyridinium chloride(HBCbpeCl),and characterized by single-crystal X-ray diffraction,IR spectroscopy,powder X-ray diffraction and thermogravimetric analysis,respectively.In the solid state,the BCbpe ligands are packed in a head-to-tail manner through weak cation-π interaction,undergoing a photo-induced cycloaddition quantitatively upon UV-light irradiation.
文献关键词：
中图分类号：
作者姓名：
JIA Mengze;SUN Li;CHEN Yunrui;ZHANG Jie
作者机构：
MOE Key Laboratory of Cluster Science,Beijing Key Laboratory of Photo-electronic/Electrophotonic Conversion Materials,School of Chemistry and Chemical Engineering,Beijing Institute of Technology,Beijing 102488,P.R.China;College of Chemical Engineering,Shijiazhuang University,Shijiazhuang 050035,P.R.China
文献出处：
引用格式：
[1]JIA Mengze;SUN Li;CHEN Yunrui;ZHANG Jie-.Solid-state [2+2] Photocycloaddition Reaction of Zinc(Ⅱ)Complex Based on Quaternized 1,2-Bis(4'-pyridyl)ethylene)[J].高等学校化学研究（英文版）,2022(01):181-185
A类：
Photocycloaddition,Quaternized,BCbpe,carboxybenzyl,HBCbpeCl
B类：
Solid,state,2+2,Reaction,Zinc,Complex,Based,Bis,pyridyl,ethylene,photoactive,metal,organic,complex,Zn2,DBC,5H2O,has,been,synthesized,olefin,containing,pyridinium,compound,vinyl,chloride,characterized,by,single,crystal,ray,diffraction,spectroscopy,powder,thermogravimetric,analysis,respectively,In,solid,ligands,are,packed,head,tail,manner,through,weak,cation,interaction,undergoing,induced,quantitatively,upon,UV,light,irradiation
AB值：
0.681427
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