典型文献
A New Tubular Borate Built by [B14O24(OH)6]12-Cluster Units
文献摘要：
A new mixed alkali and alkaline-earth metal borate Na4Ca2[B14O22(OH)6]·2H2O(1) has been made under a mild solvothermal condition and characterized by single-crystal X-ray diffraction,infrared(IR) spectroscopy,UV-Vis diffuse reflec-tance spectroscopy,powder X-ray diffraction and thermogravimetric analysis,respectively.Compound 1.features a 11D tube based on[B14O24(OH)6]12-({B14}-1) oxo-boron clusters.Such a tube built by{B14}-1 units has been discovered for the first time in borate system.These tubes are arranged orderly to generate 2D layers and a further 3D supramolecular network through hydrogen bond interactions.UV-Vis diffuse reflectance spectrum reveals that compound 1 is a wide band-gap semiconductor and has potential application in UV region.
文献关键词：
中图分类号：
作者姓名：
SUN Xiao-Shuang;QIN Dan;LI Xu-Yan;YANG Guo-Yu
作者机构：
Key Laboratory of Cluster Science,Ministry of Education,School of Chemis-try and Chemical Engineering,Beijing Institute of Technology,Beijing 100081,P.R.China
文献出处：
引用格式：
[1]SUN Xiao-Shuang;QIN Dan;LI Xu-Yan;YANG Guo-Yu-.A New Tubular Borate Built by [B14O24(OH)6]12-Cluster Units)[J].高等学校化学研究（英文版）,2022(01):123-127
A类：
B14O24,Na4Ca2,B14O22
B类：
New,Tubular,Borate,Built,by,Cluster,Units,new,mixed,alkaline,earth,metal,borate,2H2O,has,been,made,under,mild,solvothermal,condition,characterized,single,crystal,ray,diffraction,infrared,spectroscopy,UV,Vis,diffuse,powder,thermogravimetric,analysis,respectively,Compound,features,11D,oxo,boron,clusters,Such,built,units,discovered,first,system,These,tubes,arranged,orderly,generate,2D,layers,further,supramolecular,network,through,hydrogen,bond,interactions,reflectance,spectrum,reveals,that,compound,wide,band,gap,semiconductor,potential,application,region
AB值：
0.652318
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