典型文献
Benzobisthiazole Polymer with Resonance-assisted Hydrogen Bonds for High-performance Transistor and Solar Cell Applications
文献摘要：
Benzobisthiazole polymer with resonance-assisted hydrogen bonds (RAHBs) has been synthesized for both organic field-effect transistor and polymer solar cell applications.The properties of the hydrogen bonded polymer are compared with the reference polymer without RAHBs.Single-crystal X-ray diffraction analyses of the building block reveal that the RAHB interactions are formed between the carbamate hydrogen and imine nitrogen of the thiazoles.The hydrogen donor and acceptor are connected by π-conjugated molecular framework and the hydrogen-bridged quasi aromatic rings lock the conformation of the building block.The building block adopted a layered sandwich packing in crystal instead of slipped herringbone stacking which was often found in the crystal of benzobisthiazole derivatives.The polymer PCBTZ-TT with RAHBs showed deeper HOMO/LUMO energy level (about 0.2 eV) than reference polymer.The PCBTZ-TT demonstrated the hole mobility of 0.96 cm2·V-1·s-1 in field-effect transistor devices and achieved power conversion efficiency of 13.6％ in solar cell devices with Y6 as acceptor without any additive.
文献关键词：
中图分类号：
作者姓名：
Bing-Yong Liu;Cong Xie;Cong-Wu Ge;Meng-Meng Cui;Wei Yang;Zai-Fei Ma;Xi-Ke Gao;Yin-Hua Zhou;Qing Zhang
作者机构：
Shanghai Key Laboratory of Electrical Insulation and Thermal Aging,School of Chemistry and Chemical Engineering,Shanghai Jiaotong University,Shanghai 200240,China;Wuhan National Laboratory for Optoelectronics,Huazhong University of Science and Technology,Wuhan 430074,China;Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules,Center for Excellence in Molecular Synthesis,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai200032,China;State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,Center for Advanced Low-dimension Materials,Donghua University,Shanghai 201620,China
文献出处：
引用格式：
[1]Bing-Yong Liu;Cong Xie;Cong-Wu Ge;Meng-Meng Cui;Wei Yang;Zai-Fei Ma;Xi-Ke Gao;Yin-Hua Zhou;Qing Zhang-.Benzobisthiazole Polymer with Resonance-assisted Hydrogen Bonds for High-performance Transistor and Solar Cell Applications)[J].高分子科学（英文版）,2022(02):147-156
A类：
Benzobisthiazole,RAHBs,RAHB,thiazoles,benzobisthiazole,PCBTZ
B类：
Polymer,Resonance,assisted,Hydrogen,Bonds,High,performance,Transistor,Solar,Cell,Applications,polymer,resonance,hydrogen,bonds,has,been,synthesized,both,organic,field,effect,transistor,solar,cell,applications,properties,bonded,compared,reference,without,Single,crystal,ray,diffraction,analyses,building,block,reveal,that,interactions,formed,between,carbamate,imine,nitrogen,donor,acceptor,connected,by,conjugated,molecular,framework,bridged,quasi,aromatic,rings,conformation,adopted,layered,sandwich,packing,instead,slipped,herringbone,stacking,which,was,often,found,derivatives,TT,showed,deeper,HOMO,LUMO,energy,level,about,eV,than,demonstrated,hole,mobility,devices,achieved,power,conversion,efficiency,Y6,any,additive
AB值：
0.579147
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
