典型文献
Porous Assembly of Metallo-Supramolecule and Polyoxometal-ate via Ionic Complexation with Vapor Sorption Properties
文献摘要：
Porous materials have been extensively developed and displayed special applications in diverse fields,however,it still remains a great challenge in developing new synthetic methods with features of energy-saving and easy-operating.In this study,we reported the construction of a series of novel ionic complexes based on discrete supramolecular triangle structure and polyoxometalate[Mo6O19]2-,using a quite efficient strategy.The obtained composites exhibit precise 3D network structures with ideal stability con-taining micropores,which were characterized by the 1H NMR,ESI-MS,TEM,SEM,and single-crystal X-ray diffraction.These compo-sites showed differential vapor adsorption behaviors for benzene,toluene,and cyclohexane.This work provides a novel approach for fabricating porous materials through electrostatic interactions and has great potential for gas separation.
文献关键词：
中图分类号：
作者姓名：
Yaping Xu;Hao Yu;Xin Jiang;Junjuan Shi;Bao Li;Lu Li;Lixin Wu;Ming Wang
作者机构：
State Key Laboratory of Supramolecular Structure and Materials,College of Chemistry,Jilin University,Changchun,Jilin 130012,China;State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,College of Chemistry,Jilin University,Changchun,Jilin 130012,China
文献出处：
引用格式：
[1]Yaping Xu;Hao Yu;Xin Jiang;Junjuan Shi;Bao Li;Lu Li;Lixin Wu;Ming Wang-.Porous Assembly of Metallo-Supramolecule and Polyoxometal-ate via Ionic Complexation with Vapor Sorption Properties)[J].中国化学（英文版）,2022(07):813-818
A类：
Metallo,Supramolecule,Polyoxometal,Mo6O19
B类：
Porous,Assembly,via,Ionic,Complexation,Vapor,Sorption,Properties,materials,have,been,extensively,developed,displayed,special,applications,diverse,fields,however,still,remains,great,challenge,developing,new,synthetic,methods,features,energy,saving,easy,operating,In,this,study,reported,construction,series,novel,ionic,complexes,discrete,supramolecular,triangle,polyoxometalate,using,quite,efficient,strategy,obtained,composites,exhibit,precise,network,structures,ideal,stability,taining,micropores,which,were,characterized,by,1H,NMR,ESI,TEM,single,crystal,ray,diffraction,These,showed,differential,vapor,adsorption,behaviors,benzene,toluene,cyclohexane,This,provides,approach,fabricating,porous,through,electrostatic,interactions,has,potential,gas,separation
AB值：
0.744673
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