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典型文献
Low lattice thermal conductivity and enhanced thermoelectric performance of SnTe via chemical electroless plating of Ag
文献摘要:
Interface engineering has been regarded as an effective strategy to manipulate the thermoelectric perfor-mance of materials.Here,we use a facile chemical elec-troless plating and a spark plasma sintering process to fabricate Ag-plated SnTe bulk.After sintering,a small amount of plated Ag can be doped into SnTe to suppress the Sn vacancies and the others form Ag precipitates with a size distribution from nanoscale to microscale,which introduces Ag/SnTe interfaces to enhance the Seebeck coefficient via energy filtering effect.Simultaneously,these structures result in strong scattering to reach a low lattice thermal conductivity of ~ 0.62 W·m-1·K-1.Con-sequently,a maximum figure of merit (zT) of ~ 0.67 at 823 K is achieved in 2 wt% Ag-plated SnTe,which is ~60% higher than that of pristine SnTe.Moreover,the microhardness indentation test results show that the mean microhardness of 2 wt% Ag-plated SnTe is HV 64.26,which is much higher than that of pristine SnTe,indicating that Ag electroless plating can improve the mechanical properties of SnTe.This work has provided a facile and eco-friendly method to realize the interface engineering for manipulating the thermoelectric and mechanical properties of SnTe.
文献关键词:
作者姓名:
Bang-Zhou Tian;Xu-Ping Jiang;Jie Chen;Han Gao;Ze-Gao Wang;Jun Tang;Da-Li Zhou;Lei Yang;Zhi-Gang Chen
作者机构:
School of Materials Science & Engineering,Sichuan University,Chengdu 610064,China;Key Laboratory of Material Physics of Ministry of Education,School of Physics and Microelectronics,Zhengzhou University,Zhengzhou 450052,China;Key Laboratory of Radiation Physics and Technology,Ministry of Education,Institute of Nuclear Science and Technology,Sichuan University,Chengdu 610064,China;Centre for Future Materials,University of Southern Queensland,Springfield Central,QLD 4300,Australia
引用格式:
[1]Bang-Zhou Tian;Xu-Ping Jiang;Jie Chen;Han Gao;Ze-Gao Wang;Jun Tang;Da-Li Zhou;Lei Yang;Zhi-Gang Chen-.Low lattice thermal conductivity and enhanced thermoelectric performance of SnTe via chemical electroless plating of Ag)[J].稀有金属(英文版),2022(01):86-95
A类:
troless
B类:
Low,lattice,thermal,conductivity,enhanced,thermoelectric,performance,SnTe,via,chemical,electroless,plating,Ag,Interface,engineering,has,been,regarded,effective,strategy,manipulate,materials,Here,we,use,facile,spark,plasma,sintering,process,fabricate,plated,bulk,After,small,amount,doped,into,suppress,vacancies,others,precipitates,size,distribution,from,nanoscale,microscale,which,introduces,interfaces,Seebeck,coefficient,energy,filtering,Simultaneously,these,structures,strong,scattering,reach,low,Con,sequently,maximum,figure,merit,zT,achieved,wt,higher,than,that,pristine,Moreover,microhardness,indentation,test,results,show,mean,HV,much,indicating,improve,mechanical,properties,This,work,provided,eco,friendly,method,realize,manipulating
AB值:
0.525337
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