典型文献
Cs3Bi2I9-hydroxyapatite composite waste forms for cesium and iodine immobilization
文献摘要：
Perovskite-based ceramic composites were developed as potential waste form materials for immobilizing cesium(Cs)and iodine(Ⅰ)with high waste loadings and chemical durability.The perovskite Cs3Bi2I9 has high Cs(22 wt％)and I(58 wt％)content,and thus can be used as a potential host phase to immobilize these critical radionuclides.In this work,the perovskite Cs3Bi2l9 phase was synthesized by a cost effective solution-based approach,and was embedded into a highly durable hydroxyapatite matrix by spark plasma sintering to form dense ceramic composite waste forms.The chemical durabilities of the monolithic Cs3Bi2I9 and Cs3Bi2I9-hydroxyapatite composite pellets were investigated by static and semi-dynamic leaching tests,respectively.Cs and I are incongruently released from the matrix for both pure Cs3Bi2I9 and composite structures.The normalized Cs release rate is faster than that of I,which can be explained by the difference in the strengths between Cs-I and Bi-I bonds as well as the formation of insoluble micrometer-sized BiOI precipitates.The activation energies of elemental releases based on dissolution and diffusion-controlled mechanisms are determined with significantly higher energy barriers for dissolution from the composite versus that of the monolithic Cs3Bi2I9.The ceramic-based composite waste forms exhibit excellent chemical durabilities and waste loadings,commensurate with the state-of-the-art glass-bonded perovskite composites for I and Cs immobilization.
文献关键词：
中图分类号：
作者姓名：
Kun YANG;Yachun WANG;Junhua SHEN;Spencer M.SCOTT;Brian J.RILEY;John D.VIENNA;Jie LIAN
作者机构：
Department of Mechanical,Aerospace,and Nuclear Engineering,Rensselaer Polytechnic Institute,Troy,USA;Department of Materials Science&Engineering,Rensselaer Polytechnic Institute,Troy,USA;Savannah River National Laboratory,Aiken,USA;Pacific Northwest National Laboratory,Richland,USA
文献出处：
引用格式：
[1]Kun YANG;Yachun WANG;Junhua SHEN;Spencer M.SCOTT;Brian J.RILEY;John D.VIENNA;Jie LIAN-.Cs3Bi2I9-hydroxyapatite composite waste forms for cesium and iodine immobilization)[J].先进陶瓷（英文版）,2022(05):712-728
A类：
Cs3Bi2l9,durabilities,incongruently
B类：
Cs3Bi2I9,hydroxyapatite,waste,forms,cesium,iodine,immobilization,Perovskite,ceramic,composites,were,developed,potential,materials,immobilizing,loadings,chemical,durability,perovskite,wt,content,thus,used,host,phase,immobilize,these,critical,radionuclides,In,this,work,synthesized,by,cost,effective,approach,embedded,into,highly,durable,matrix,spark,plasma,sintering,dense,monolithic,pellets,investigated,static,semi,dynamic,leaching,tests,respectively,are,released,from,both,pure,structures,normalized,faster,than,that,which,explained,difference,strengths,between,bonds,well,formation,insoluble,micrometer,BiOI,precipitates,activation,energies,elemental,releases,dissolution,diffusion,controlled,mechanisms,determined,significantly,higher,energy,barriers,versus,exhibit,excellent,commensurate,state,art,glass,bonded
AB值：
0.49943
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