Interstitial atoms that commonly occupy the octahedral or tetrahedral interstices of face-centered cubic(FCC)lattice,can significantly affect the dislocation behaviors on deformation.Recently,interstitial dop-ing has been applied to tune the mechanical properties of the emerging multicomponent,often termed high-entropy alloys(HEAs)or medium-entropy alloys(MEAs).However,the fundamental mechanisms of the dislocation nucleation and the onset of plasticity of interstitial multicomponent alloys governed by the concentration of interstitial atoms are still unclear.Therefore,in the present work,an instrumented nanoindentation was employed to investigate the interstitial concentration effects of carbon atoms on single FCC-phase equiatomic FeNiCr MEAs during loading.The results show that the pop-in events that denote the onset of incipient plasticity are triggered by the sudden heterogeneous dislocation nucleation via the primary atoms-vacancy exchange with the instant stress field,regardless of the interstitial con-centration.Moreover,the measured activation volumes for dislocation nucleation of the FeNiCr MEAs are determined to be increased with the interstitial concentration,which definitely suggests the participation of interstitial atoms in the nucleation process.Besides,it is also found that the average value measured in statistics of the maximum shear stress corresponding to the first pop-in is enhanced with the interstitial concentration.Such scenario can be attributed to the improved local change transfer and lattice cohesion caused by the interstitial atoms with higher concentrations.Furthermore,the significant drag effect of interstitial carbon atoms hinders the mobile dislocations before exhaustion,which severely suppresses the subsequent occurrence of pop-in events in the carbon-doped specimens.The work gives a microscale view of interstitial effects on the mechanical properties of multicomponent alloys,which can further help to develop new interstitial strengthening strategies for structural materials with remarkable performance.

Quanqing Zeng;Kefu Gan;Fei Chen;Dongyao Wang;Songsheng Zeng

Research Institute of Light Alloy,Central South University,Changsha 410083,China;Key Laboratory of the Ministry of Education of Nonferrous Metals,Central South University,Changsha 410083,China;School of Materials Science and Engineering,Central South University,Changsha 410083,China

材料科学技术（英文版）

[1]Quanqing Zeng;Kefu Gan;Fei Chen;Dongyao Wang;Songsheng Zeng-.Interstitial concentration effects on incipient plasticity and dislocation behaviors of face-centered cubic FeNiCr multicomponent alloys based on nanoindentation)[J].材料科学技术（英文版）,2022(17):212-221

FeNiCr,interstices

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