典型文献
Mn-mediated reductive C(sp3)-Si coupling of activated secondary alkyl bromides with chlorosilanes
文献摘要：
The construction of secondary alkylsilanes is a challenging subject in the synthetic community.The cross-coupling provides a practical solution to address this problem,but it typically relies on organometallic species.Herein,we report an Mn-mediated reductive C(sp3)-Si coupling to synthesize these compounds from alkyl and silyl electrophiles.This approach avoids the requirement for activation of Si-Cl by tran-sition metals and thus allows for the coupling of various common chlorosilanes.The reaction proceeds under mild conditions and shows good functional group compatibility.The method offers access to α-silylated organophosphorus and sulfones with a scope that is complementary to those obtained from the established methods.
文献关键词：
中图分类号：
作者姓名：
Liangliang Qi;Xiaobo Pang;Kai Yin;Qiu-Quan Pan;Xiao-Xue Wei;Xing-Zhong Shu
作者机构：
State Key Laboratory of Applied Organic Chemistry(SKLAOC),College of Chemistry and Chemical Engineering,Lanzhou University,Lanzhou 730000,China;School of Chemistry and Chemical Engineering,Southeast University,Jiangsu Optoelectronic Functional Materials and Engineering Laboratory,Nanjing 211189,China;Zhejiang Nanjiao Chemistry Co.,Ltd.,Shangyu Economic and Technological Development Zone,Shangyu 312369,China
文献出处：
引用格式：
[1]Liangliang Qi;Xiaobo Pang;Kai Yin;Qiu-Quan Pan;Xiao-Xue Wei;Xing-Zhong Shu-.Mn-mediated reductive C(sp3)-Si coupling of activated secondary alkyl bromides with chlorosilanes)[J].中国化学快报（英文版）,2022(12):5061-5064
A类：
chlorosilanes,alkylsilanes,silyl,sulfones
B类：
Mn,mediated,reductive,sp3,Si,coupling,activated,secondary,bromides,construction,challenging,subject,synthetic,community,cross,provides,practical,solution,address,this,problem,but,typically,relies,organometallic,species,Herein,we,report,synthesize,these,compounds,from,electrophiles,This,approach,avoids,requirement,activation,Cl,by,tran,sition,metals,thus,allows,various,common,reaction,proceeds,under,mild,conditions,shows,good,functional,group,compatibility,offers,access,silylated,organophosphorus,scope,that,complementary,those,obtained,established,methods
AB值：
0.641983
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