典型文献
N-heterocyclic carbene-stabilized metal nanoparticles within porous organic cages for catalytic application
文献摘要：
Tuning the surface-embellishing ligands of metal nanoparticles(NPs)is a powerful strategy to modulate their morphology and surface electronic and functional features,impacting their catalytic activity and selectivity.In this work,we report the design and synthesis of a polytriazolium organic cage PIC-T,capable of stabilizing PdNPs within its discrete cavity.The obtained material(denoted Pd@PCC-T)is highly durable and monodispersed with narrow particle-size distribution of 2.06±0.02 nm,exhibiting excellent catalytic performance and recyclability in the Sonogashira coupling and tandem reaction to synthesize benzofuran derivatives.Further investigation indicates that the modulation of N-heterocyclic carbene sites embedded in the organic cage has an impact on NPs'catalytic efficiency,thus providing a novel methodology to design superior NP catalysts.
文献关键词：
中图分类号：
作者姓名：
Tong Liu;Sha Bai;Le Zhang;F.Ekkehardt Hahn;Ying-Feng Han
作者机构：
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education,Xi'an Key Laboratory of Functional Supramolecular Structure and Materials,College of Chemistry and Materials Science,Northwest University,Xi'an 710127,China;Institut für Anorganicshe und Analytische Chemie,Westf?lische Wilhelms-Universit?t Munster,Munster 48149,Germany
文献出处：
引用格式：
[1]Tong Liu;Sha Bai;Le Zhang;F.Ekkehardt Hahn;Ying-Feng Han-.N-heterocyclic carbene-stabilized metal nanoparticles within porous organic cages for catalytic application)[J].国家科学评论（英文版）,2022(06):130-137
A类：
embellishing,polytriazolium,benzofuran
B类：
heterocyclic,carbene,stabilized,metal,nanoparticles,within,porous,organic,cages,catalytic,application,Tuning,surface,ligands,powerful,strategy,modulate,their,morphology,electronic,functional,features,impacting,activity,selectivity,In,this,work,report,design,synthesis,PIC,capable,stabilizing,PdNPs,its,discrete,cavity,obtained,material,denoted,PCC,highly,durable,monodispersed,narrow,distribution,exhibiting,excellent,performance,recyclability,Sonogashira,coupling,tandem,reaction,synthesize,derivatives,Further,investigation,indicates,that,modulation,sites,embedded,has,efficiency,thus,providing,novel,methodology,superior,catalysts
AB值：
0.636603
相似文献
机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
