典型文献
Construction of N-doped carbon frames anchored with Co single atoms and Co nanoparticles as robust electrocatalyst for hydrogen evolution in the entire pH range
文献摘要：
The development of low-cost,efficient,and high atomic economy electrocatalysts for hydrogen evolution reaction(HER)in the entire pH range for sustainable hydrogen production is of great importance but still challenging.Herein,we synthesize a highly dispersed N-doped carbon frames(NCFs)anchored with Co single atoms(SAs)and Co nanoparticles(NPs)catalyst by a doping-adsorption-pyrolysis strategy for elec-trocatalytic hydrogen evolution.The Co SAs-Co NPs/NCFs catalyst exhibits an excellent HER activity with small overpotential,low Tafel slope,high turnover frequency as well as remarkable stability.It also exhi-bits a superior HER performance in the entire pH range.Combining with experimental and theoretical calculation,we find that Co SAs with Co-N3 coordination structure and Co NPs have a strong interaction for promoting synergistic HER electrocatalytic process.The H2O molecule is easily activated and dissoci-ated on Co NPs,while the generated H* is easily adsorbed on Co SAs for HER,which makes the Co SAs-Co NPs/NCFs catalyst exhibit more suitable H adsorption strength and more conducive to the activation and dissociation of H2O molecules.This work not only proposes a novel idea for constructing coupling catalyst with atomic-level precision,but also provides strong reference for the development of high-efficiency HER electrocatalysts for practical application.
文献关键词：
中图分类号：
作者姓名：
Minmin Wang;Min Li;Yilin Zhao;Naiyou Shi;Hui Zhang;Yuxue Zhao;Yaru Zhang;Haoran Zhang;Wenhong Wang;Kaian Sun;Yuan Pan;Shoujie Liu;Houyu Zhu;Wenyue Guo;Yanpeng Li;Yunqi Liu;Chenguang Liu
作者机构：
State Key Laboratory of Heavy Oil Processing,China University of Petroleum(East China),Qingdao 266580,Shandong,China;School of Materials Science and Engineering,China University of Petroleum(East China),Qingdao 266580,Shandong,China;College of Chemistry and Materials Science,Anhui Normal University,Wuhu 241000,Anhui,China
文献出处：
引用格式：
[1]Minmin Wang;Min Li;Yilin Zhao;Naiyou Shi;Hui Zhang;Yuxue Zhao;Yaru Zhang;Haoran Zhang;Wenhong Wang;Kaian Sun;Yuan Pan;Shoujie Liu;Houyu Zhu;Wenyue Guo;Yanpeng Li;Yunqi Liu;Chenguang Liu-.Construction of N-doped carbon frames anchored with Co single atoms and Co nanoparticles as robust electrocatalyst for hydrogen evolution in the entire pH range)[J].能源化学,2022(04):147-156
A类：
NCFs,dissoci
B类：
Construction,doped,carbon,frames,anchored,single,atoms,nanoparticles,robust,hydrogen,evolution,entire,range,development,low,cost,efficient,atomic,economy,electrocatalysts,reaction,HER,sustainable,production,great,importance,but,still,challenging,Herein,synthesize,highly,dispersed,SAs,NPs,by,doping,adsorption,pyrolysis,strategy,exhibits,excellent,activity,small,overpotential,Tafel,slope,turnover,frequency,well,remarkable,stability,It,also,superior,performance,Combining,experimental,theoretical,calculation,find,that,N3,coordination,structure,have,strong,interaction,promoting,synergistic,electrocatalytic,process,H2O,easily,activated,while,generated,adsorbed,which,makes,more,suitable,strength,conducive,activation,dissociation,molecules,This,work,not,only,proposes,novel,idea,constructing,coupling,level,precision,provides,reference,efficiency,practical,application
AB值：
0.492573
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
