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典型文献
Regioselective 2-alkylation of indoles with α-bromo esters catalyzed by Pd/P,P=O system
文献摘要:
A palladium-catalyzed 2-alkylation of indoles with α-bromo esters is developed by employing a P,P=O ligand.The method features excellent regioselectivities,mild reaction conditions,and good functional group compatibility.The employment of the P,P=O ligand as well as 4 (A) molecular sieves were crucial for the success of the transformation.Mechanistic studies indicate the reaction proceed through a radical pathway.
文献关键词:
作者姓名:
Wei Tian;Bowen Li;Duanshuai Tian;Wenjun Tang
作者机构:
State Key Laboratory of Bio-Organic and Natural Products Chemistry,Center for Excellence in Molecular Synthesis,Shanghai Institute of Organic Chemistry,University of Chinese Academy of Sciences,Shanghai 200032,China;School of Chemistry and Material Sciences,Hangzhou Institute for Advanced Study,University of Chinese Academy of Sciences,Hangzhou 310024,China
引用格式:
[1]Wei Tian;Bowen Li;Duanshuai Tian;Wenjun Tang-.Regioselective 2-alkylation of indoles with α-bromo esters catalyzed by Pd/P,P=O system)[J].中国化学快报(英文版),2022(01):197-200
A类:
Regioselective,regioselectivities
B类:
alkylation,indoles,bromo,esters,catalyzed,by,Pd,system,palladium,developed,employing,ligand,method,features,excellent,mild,reaction,conditions,good,functional,group,compatibility,employment,as,well,molecular,sieves,were,crucial,success,transformation,Mechanistic,studies,indicate,proceed,through,radical,pathway
AB值:
0.64507
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