典型文献
Kinetics study of the N-formylation of aniline with DMF catalyzed by temperature-controlled Br?nsted ionic liquids
文献摘要：
A series of SO3-functional Br?nsted acidic ionic liquids(SBAILs)were prepared to catalyze the N-formylation of aniline with DMF.The reaction conditions such as ionic liquid type,reaction temperature,catalyst loading and molar ratio of reactants were investigated.To the best of our knowledge,kinetic model for the N-formylation of aniline with DMF using SBAIL was firstly built and simulated.The studies on the reaction order of the reaction were evaluated by initial concentration method,and the kinetic parameters such as reaction rate constant and activation energy were proposed and used to explain the catalytic activities of the SBAILs catalysts.Accordingly,the recycling experiments showed that the SBAIL[Bsmim][HSO4]can be easily recovered and reused with stable activity.Further,the temperature-controlled study emphasized that the ionic liquid was easy to be separated and environ-mentally friendly.
文献关键词：
中图分类号：
作者姓名：
Yipeng Zheng;Zhennan Cao;Zheng Zhou;Gaodong Yang;Zhibing Zhang
作者机构：
School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210023,China
文献出处：
引用格式：
[1]Yipeng Zheng;Zhennan Cao;Zheng Zhou;Gaodong Yang;Zhibing Zhang-.Kinetics study of the N-formylation of aniline with DMF catalyzed by temperature-controlled Br?nsted ionic liquids)[J].中国化学工程学报（英文版）,2022(12):154-160
A类：
formylation,SBAILs,SBAIL,Bsmim
B类：
Kinetics,study,aniline,DMF,catalyzed,by,temperature,controlled,Br,nsted,ionic,liquids,series,SO3,functional,acidic,were,prepared,reaction,conditions,such,type,loading,molar,reactants,investigated,To,best,our,knowledge,kinetic,model,using,was,firstly,built,simulated,studies,order,evaluated,initial,concentration,method,parameters,constant,activation,energy,proposed,explain,catalytic,activities,catalysts,Accordingly,recycling,experiments,showed,that,HSO4,can,easily,recovered,reused,stable,activity,Further,emphasized,easy,separated,environ,mentally,friendly
AB值：
0.504447
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