典型文献
Metal-organic frameworks derived transition metal phosphides for electrocatalytic water splitting
文献摘要：
It is critical to synthesize high-efficiency electrocatalysts to boost the performance of water splitting to meet the requirements of industrial applications.Metal-organic frameworks(MOFs)can function as ideal molecular platforms for the design of highly reactive transition metal phosphides(TMPs),a kind of can-didates for high-efficiently electrocatalytic water splitting.The intrinsic activity of the electrocatalysts can be greatly improved via modulating the electronic structure of the catalytic center through the MOF precursors/templates.Moreover,the carbon layer converted in-situ by the organic ligands can not only protect the TMPs from being degraded in the harsh electrochemical environments,but also avoid agglomeration of the catalysts,thereby promoting their activities and stabilities.Furthermore,heteroatom-containing ligands can incorporate N,S or P,etc.atoms into the carbon matrixes after con-version,regulating the coordination microenvironments of the active centers as well as their electronic structures.In this review,we first summarized the latest developments in MOF-derived TMPs by the unique advantages in metal,organic ligand,and morphology regulations for electrocatalytic water split-ting.Secondly,we concluded the critical scientific issues currently facing for designing state-of-the-art TMP-based electrocatalysts.Finally,we presented an outlook on this research area,encompassing elec-trocatalyst construction,catalytic mechanism research,etc.
文献关键词：
中图分类号：
作者姓名：
Li-Ming Cao;Jia Zhang;Li-Wen Ding;Zi-Yi Du;Chun-Ting He
作者机构：
Key Laboratory of Functional Small Molecules for Ministry of Education,College of Chemistry and Chemical Engineering,Jiangxi Normal University,Nanchang 330022,Jiangxi,China;Key Laboratory for Green Chemistry of Jiangxi Province,Nanchang 330022,Jiangxi,China
文献出处：
引用格式：
[1]Li-Ming Cao;Jia Zhang;Li-Wen Ding;Zi-Yi Du;Chun-Ting He-.Metal-organic frameworks derived transition metal phosphides for electrocatalytic water splitting)[J].能源化学,2022(05):494-520
A类：
B类：
Metal,organic,frameworks,derived,transition,metal,phosphides,electrocatalytic,water,splitting,It,critical,synthesize,efficiency,electrocatalysts,boost,performance,meet,requirements,industrial,applications,MOFs,can,function,ideal,molecular,platforms,highly,reactive,TMPs,kind,didates,efficiently,intrinsic,activity,greatly,improved,via,modulating,electronic,through,precursors,templates,Moreover,carbon,layer,converted,situ,ligands,not,only,protect,from,being,degraded,harsh,electrochemical,but,also,avoid,agglomeration,thereby,promoting,their,activities,stabilities,Furthermore,heteroatom,containing,incorporate,etc,atoms,into,matrixes,after,version,regulating,coordination,microenvironments,centers,well,structures,In,this,review,first,summarized,latest,developments,unique,advantages,morphology,regulations,Secondly,concluded,scientific,issues,currently,facing,designing,state,art,Finally,presented,outlook,research,area,encompassing,construction,mechanism
AB值：
0.574101
相似文献
机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
