To date,Co-based metal-organic frameworks (Co-MOFs) have drawn much attention owing to their ad-vantages of easy preparation,high porosity and adjustable structure.Because of these enticing properties,numerous efforts have been devoted to their applications in energy storage and conversion.However,poor conductivity has become one of the biggest obstacles for large-scale use of pristine Co-MOFs.Sub-sequently,many attempts have been carried out to develop various Co-MOF derived materials as elec-trodes for rechargeable batteries in order to address the above-mentioned shortcoming and to enhance the electrical conductivity with improved stability during cycling.Moreover,in addition to improvement of Li-ion batteries in practical utilization,seeking for other rechargeable batteries is another urgent task due to the high cost and limited sources of metallic Li.Herein,by following the recent research progress,this review provides an overview of applications of Co-MOF derived materials in various rechargeable batteries including lithium-ion batteries,sodium-ion batteries,lithium-sulfur batteries,zinc air batteries and other rechargeable batteries,where they have been utilized as cathodes,anodes,separators and elec-trocatalysts.Accordingly,we categorize and compare the morphology driven electrochemical performance of various Co-MOF derivatives including porous carbon,cobalt oxides,cobalt chalcogenides,cobalt phos-phides and corresponding composites.Finally,current challenges for large-scale production and commer-cialization of Co-MOF derived materials as well as some reasonable solutions have been discussed at the end.

Jianen Zhou;Qingyun Yang;Qiongyi Xie;Hong Ou;Xiaoming Lin;Akif Zeb;Lei Hu;Yongbo Wu;Guozheng Ma

Guangzhou Key Laboratory of Materials for Energy Conversion and Storage,Key Laboratory of Theoretical Chemistry of Environment,Ministry of Education,School of Chemistry,South China Normal University,Guangzhou 510006,China;Anhui Province Key Laboratory of Functional Coordinated Complexes for Materials Chemistry and Application,School of Chemical and Environmental Engineering,Anhui Polytechnic University,Wuhu 241000,China;School of Physics and Telecom Engineering,South China Normal University,Guangzhou 510006,China

材料科学技术（英文版）

[1]Jianen Zhou;Qingyun Yang;Qiongyi Xie;Hong Ou;Xiaoming Lin;Akif Zeb;Lei Hu;Yongbo Wu;Guozheng Ma-.Recent progress in Co-based metal-organic framework derivatives for advanced batteries)[J].材料科学技术（英文版）,2022(01):262-284

phides

Recent,progress,Co,organic,derivatives,advanced,batteries,To,date,frameworks,MOFs,have,drawn,much,attention,their,vantages,easy,preparation,high,porosity,adjustable,structure,Because,these,enticing,properties,numerous,efforts,been,devoted,applications,energy,storage,conversion,However,poor,conductivity,has,become,biggest,obstacles,large,scale,pristine,Sub,sequently,many,attempts,carried,out,develop,various,derived,materials,trodes,rechargeable,order,address,above,mentioned,shortcoming,enhance,electrical,improved,stability,during,cycling,Moreover,addition,improvement,Li,practical,utilization,seeking,another,urgent,task,due,cost,limited,sources,metallic,Herein,by,following,recent,research,this,review,provides,overview,including,lithium,sodium,sulfur,zinc,air,where,they,utilized,cathodes,anodes,separators,trocatalysts,Accordingly,categorize,compare,morphology,driven,electrochemical,performance,porous,carbon,cobalt,oxides,chalcogenides,phos,corresponding,composites,Finally,current,challenges,production,commer,cialization,well,some,reasonable,solutions,discussed,end

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