典型文献
Rb5Ba2(B10O17)2(BO2):The formation of unusual functional[BO2]in borates with deep-ultraviolet transmission window
文献摘要：
The design and synthesis of new deep-ultraviolet(DUV)optical materials are important but challenging.It is well known that the polarizability anisotropy of linear[BO2]is larger than those of[BO3]3-and[BO4]5-,which is the better choice for exploring excellent optical materials.Here,we search for such crystals in borate systems based on the unusual fundamental structural unit[BO2]-.By combining the linear[BO2]-with the traditional triangular[BO3]3-and tetrahedral[BO4]5-units,a new mixed metal borate,Rb5Ba2(B10O17)2(BO2)was obtained via high-temperature solution method.It exhibits excellent optical properties including a DUV transmission window(188 nm)and suitable birefringence(0.06).It also has good thermal stability and its crystal plates can be prepared easily.Furthermore,the strategies of designing borates with[BO2]-units have been proposed from the transformation of crystal framework and the preparation method.
文献关键词：
中图分类号：
作者姓名：
Yanhui Zhang;Fuming Li;Rong Yang;Yun Yang;Fangfang Zhang;Zhihua Yang;Shilie Pan
作者机构：
CAS Key Laboratory of Functional Materials and Devices for Special Environments,Xinjiang Technical Institute of Physics&Chemistry,Chinese Academy of Sciences,Xinjiang Key Laboratory of Electronic Information Materials and Devices,Urumqi 830011,China;Center of Materials Science and Optoelectronics Engineering,University of Chinese Academy of Sciences,Beijing 100049,China
文献出处：
引用格式：
[1]Yanhui Zhang;Fuming Li;Rong Yang;Yun Yang;Fangfang Zhang;Zhihua Yang;Shilie Pan-.Rb5Ba2(B10O17)2(BO2):The formation of unusual functional[BO2]in borates with deep-ultraviolet transmission window)[J].中国科学:化学（英文版）,2022(04):719-725
A类：
Rb5Ba2,B10O17
B类：
BO2,unusual,functional,borates,deep,ultraviolet,transmission,window,synthesis,new,DUV,optical,materials,important,but,challenging,It,well,known,that,polarizability,anisotropy,linear,larger,than,those,BO3,BO4,which,better,choice,exploring,excellent,Here,search,such,crystals,systems,fundamental,structural,By,combining,traditional,triangular,tetrahedral,units,mixed,metal,was,obtained,via,high,temperature,solution,method,exhibits,properties,including,suitable,birefringence,also,has,good,thermal,stability,plates,can,prepared,easily,Furthermore,strategies,designing,have,been,proposed,from,transformation,framework,preparation
AB值：
0.536457
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
