典型文献
(NH4)3B11PO19F3:a deep-UV nonlinear optical crystal with unique[B5PO10F]∞ layers
文献摘要：
Deep-ultraviolet(DUV)nonlinear optical(NLO)crystals that can extend the output range of coherent light below 200 nm are pivotal materials for solid-state lasers.To date,KBe2BO3F2(KBBF)is the only usable crystal that can generate DUV coherent light by direct second harmonic generation(SHG),but the layered growth habit and toxic ingredients limit its application.Herein,we report a new fluoroborophosphate,(NH4)3B11PO19F3(ABPF),containing four different functional units:[BO3],[BO4],[BO3F]and[PO4].ABPF exhibits a KBBF-like structure while eliminating the limitations of KBBF crystal.The unique[B5PO10F]∞ layers enhance ABPF's performance;for example,it has a large SHG response(1.2 x KDP)and a sufficient birefringence(0.088 at 1064 nm)that enables the shortest phase-matching wavelength to reach the DUV region.Meanwhile,the introduction of strong B-O-P covalent bonds decreases the layered growth habit.These findings will enrich the structural chemistry of fluoroborophosphate and contribute to the discovery of more excellent DUV NLO crystals.
文献关键词：
中图分类号：
作者姓名：
Bingliang Cheng;Zijian Li;Yu Chu;Abudukadi Tudi;Miriding Mutailipu;Fangfang Zhang;Zhihua Yang;Shilie Pan
作者机构：
CAS Key Laboratory of Functional Materials and Devices for Special Environments,Xinjiang Technical Institute of Physics and Chemistry of Chinese Academy of Sciences,Xinjiang Key Laboratory of Electronic Information Materials and Devices,Urumqi 830011,China;Center of Materials Science and Optoelectronics Engineering,University of Chinese Academy of Sciences,Beijing 100049,China
文献出处：
引用格式：
[1]Bingliang Cheng;Zijian Li;Yu Chu;Abudukadi Tudi;Miriding Mutailipu;Fangfang Zhang;Zhihua Yang;Shilie Pan-.(NH4)3B11PO19F3:a deep-UV nonlinear optical crystal with unique[B5PO10F]∞ layers)[J].国家科学评论（英文版）,2022(08):129-134
A类：
3B11PO19F3,B5PO10F,KBe2BO3F2,KBBF,fluoroborophosphate,ABPF,BO3F
B类：
NH4,deep,nonlinear,optical,unique,layers,Deep,ultraviolet,DUV,NLO,crystals,that,can,extend,output,range,coherent,light,below,are,pivotal,materials,solid,state,lasers,To,date,only,usable,generate,by,direct,second,harmonic,generation,SHG,layered,growth,habit,toxic,ingredients,application,Herein,we,report,new,containing,four,different,functional,units,BO4,PO4,exhibits,like,structure,eliminating,limitations,enhance,performance,example,large,response,KDP,sufficient,birefringence,enables,shortest,phase,matching,wavelength,reach,region,Meanwhile,introduction,strong,covalent,bonds,decreases,These,findings,will,enrich,structural,chemistry,contribute,discovery,more,excellent
AB值：
0.54532
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