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典型文献
Bicontinuous porous membranes with micro-nano composite structure using a facile atomization-assisted nonsolvent induced phase separation method
文献摘要:
The micro-nano composite structure can endow separation membranes with special surface proper-ties,but it often has the problems of inefficient preparation process and poor structural stability.In this work,a novel atomization-assisted nonsolvent induced phase separation method,which is also highly efficient and very simple,has been developed.By using this method,a bicontinuous porous microfiltration membrane with robust micro-nano composite structure was obtained via commercially available polymers of polyacrylonitrile and polyvinylpyr-rolidone.The formation mechanism of the micro-nano composite structure was proposed.The microphase separation of polyacrylonitrile and polyvinylpyrrolidone components during the atomization pretreatment process and the hydrogen bonding between polyacrylonitrile and polyvinylpyrrolidone molecules should have resulted in the nano-protrusions on the membrane skeleton.The membrane exhibits superhydrophilicity in air and super-oleophobicity underwater.The membrane can separate both surfactant-free and surfactant-stabilized oil-in-water emulsions with high separation efficiency and permeation flux.With excellent antifouling property and robust microstructure,the membrane can easily be recycled for long-term separation.Furthermore,the scale-up verifica-tion from laboratory preparation to continuous production has been achieved.The simple,efficient,cost-effective preparation method and excellent membrane properties indicate the great potential of the developed membranes in practical applications.
文献关键词:
作者姓名:
Jing Wang;Guoyuan Pan;Yu Li;Yang Zhang;Hongwei Shi;Xuanbo Liu;Hao Yu;Muhua Zhao;Yiqun Liu;Changjiang Wu
作者机构:
College of Materials Science and Engineering,Beijing University of Chemical Technology,Beijing 100029,China;SINOPEC Beijing Research Institute of Chemical Industry,Beijing 100013,China
引用格式:
[1]Jing Wang;Guoyuan Pan;Yu Li;Yang Zhang;Hongwei Shi;Xuanbo Liu;Hao Yu;Muhua Zhao;Yiqun Liu;Changjiang Wu-.Bicontinuous porous membranes with micro-nano composite structure using a facile atomization-assisted nonsolvent induced phase separation method)[J].化学科学与工程前沿,2022(08):1268-1280
A类:
Bicontinuous,nonsolvent,bicontinuous,polyvinylpyr,rolidone,oleophobicity
B类:
porous,membranes,nano,composite,using,facile,atomization,assisted,induced,separation,method,can,endow,special,surface,but,often,problems,inefficient,preparation,process,poor,structural,stability,In,this,work,novel,which,also,highly,very,simple,been,developed,By,microfiltration,robust,was,obtained,via,commercially,available,polymers,polyacrylonitrile,formation,mechanism,proposed,microphase,polyvinylpyrrolidone,components,during,pretreatment,hydrogen,bonding,between,molecules,should,have,resulted,protrusions,skeleton,exhibits,superhydrophilicity,air,underwater,separate,both,surfactant,free,stabilized,oil,emulsions,efficiency,permeation,flux,With,excellent,antifouling,property,microstructure,easily,recycled,long,term,Furthermore,scale,verifica,from,laboratory,production,achieved,cost,effective,properties,indicate,great,potential,practical,applications
AB值:
0.502828
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