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典型文献
Synthesis and optical properties of novel Gd3+-doped BaZn2(PO4)2 glass-ceramics for radiation detection applications
文献摘要:
45P2O5-15BaO-25ZnO-15B2O3 glasses doped with different concentrations(0 mol%,0.1 mol%,0.25 mol%,0.5 mol%,and 0.75 mol%)of Gd3+were prepared by a melt-quenching method and treated to fabricate glass-ceramics containing BaZn2(PO4)2 crystals by controllable crystallization.The struc-tural,optical,and dosimetric properties were investigated.FTIR spectra indicate that the glasses are composed of[PO4],[BO3],and[BO4]basic structural units.The XRD pattern analysis indicates that the samples contain BaZn2(PO4)2 crystals.In the photoluminescence(PL)spectra,two emission bands are observed at 307 and 313 nm due to the 6P5/2→857/2 and 6P7/2→8S7/2 transitions of Gd3+,respectively.The OSL dosimetric properties of glass-ceramics were studied further under beta radiation of 90Sr.The optimal Gd3+doping concentration of 0.5 mol%was determined.The fading of the OSL signal shows that the CW-OSL signal of Gd3+-doped BaZn2(PO4)2 glass-ceramics decays by about 58.95%within 120 h,and the intensity remains stable thereafter.The thermoluminescence(TL)curve has three peaks at 164,240,and 344℃.Minimum detectable dose(MDD)of the 0.5 mol%Gd3+-doped BaZn2(PO4)2 glass-ceramics was calculated as 0.675 mGy.The samples also exhibit good signal reusability and a broad linear dose-response range(0.3-500 Gy).Results show the excellent dosimetric properties of Gd3+-doped BaZn2(PO4)2 glass-ceramics and their potential application in radiation dosimetry.
文献关键词:
作者姓名:
Wanli Li;Zhaoyang Chen;Jie Xu;Pengjun Zhao;Yanwei Fan;Chengfa He
作者机构:
Key Laboratory of Functional Materials and Devices for Special Environments of CAS.Xinjiang Key Laboratory of Electronic Information Materials and Devices,Xinjiang Technical Institute of Physics&Chemistry of CAS,Urumqi 830011,China;University of Chinese Academy of Sciences,Beijing 100049,China;Center of Materials Science and Optoelectronics Engineering,University of Chinese Academy of Sciences,Beijing 100049,China;Laboratory of Solid-State Radiation Physics,Urumqi 830011,China
引用格式:
[1]Wanli Li;Zhaoyang Chen;Jie Xu;Pengjun Zhao;Yanwei Fan;Chengfa He-.Synthesis and optical properties of novel Gd3+-doped BaZn2(PO4)2 glass-ceramics for radiation detection applications)[J].稀土学报(英文版),2022(12):1927-1934
A类:
BaZn2,45P2O5,15BaO,25ZnO,15B2O3,Gd3+were,6P5,6P7,8S7,Gd3+doping,thermoluminescence
B类:
Synthesis,optical,properties,novel,doped,PO4,ceramics,radiation,detection,applications,glasses,different,concentrations,prepared,by,melt,quenching,method,treated,fabricate,containing,crystals,controllable,crystallization,dosimetric,investigated,FTIR,spectra,that,composed,BO3,BO4,basic,structural,units,pattern,analysis,indicates,samples,In,photoluminescence,PL,two,emission,bands,observed,due,transitions,respectively,OSL,studied,further,under,beta,90Sr,optimal,was,determined,fading,signal,shows,CW,decays,about,within,intensity,remains,stable,thereafter,TL,curve,has,three,peaks,Minimum,detectable,dose,MDD,calculated,mGy,also,exhibit,good,reusability,broad,linear,response,range,Results,excellent,their,potential,dosimetry
AB值:
0.43526
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