Power conversion efficiency(PCE)of perovskite solar cells(PSC)has been skyrocketed to certified 25.5％owing to their improved and tunable optoelectronic properties.Although,various strategies have been adopted to date regarding PCE and stability enhancement within PSC technology,certain instability fac-tors(moisture,heat,light)are hindering their commercial placement.Recently,all-inorganic PSCs got hype in the photovoltaic research community after they attained PCE＞20％and due to their significant endurance against heat and light mishmashes,but there only left moisture sensitivity as the only road-block for their industrial integration.Here,we review the recent progress of additive inclusion into all-inorganic(CsPbX3)PSCs to stabilize their intrinsic structure and to withstand the performance limiting factors.We start with the detailed description of chemical instability of different perovskite composi-tions,phase segregation,and how organic molecules and dyes help to repair the structural defects to improve the overall PCE and stability of PSCs.Moisture endurance as a result of chemical passivation through organic additives,low-dimensional inorganic PSCs to enhance device stability and scalable fab-rication of CsPbX3 PSCs are also reviewed.The challenges of module degradation and design implications with proposed strategies and outlook are interpreted in the ending phrases of this review.

Yameen Ahmed;Bilawal Khan;M.Bilal Faheem;Keqing Huang;Yuanji Gao;Junliang Yang

State Key Laboratory of Powder Metallurgy,School of Physics and Electronics,Central South University,Changsha 410083,Hunan,China;Department of Materials Science and Engineering,City University of Hongkong,Hongkong 999077,China;Institute of Fundamental and Frontier Sciences,University of Electronic Science and Technology of China,Chengdu 610054,Sichuan,China

能源化学

[1]Yameen Ahmed;Bilawal Khan;M.Bilal Faheem;Keqing Huang;Yuanji Gao;Junliang Yang-.Organic additives in all-inorganic perovskite solar cells and modules:from moisture endurance to enhanced efficiency and operational stability)[J].能源化学,2022(04):361-390

skyrocketed,mishmashes

Organic,additives,inorganic,perovskite,solar,cells,modules,from,moisture,endurance,enhanced,efficiency,operational,Power,conversion,PCE,been,certified,owing,their,improved,tunable,optoelectronic,properties,Although,various,strategies,have,adopted,date,regarding,enhancement,within,technology,certain,instability,heat,light,are,hindering,commercial,placement,Recently,PSCs,got,hype,photovoltaic,research,community,after,they,attained,due,significant,against,but,there,only,left,sensitivity,road,block,industrial,integration,Here,recent,progress,inclusion,into,CsPbX3,stabilize,intrinsic,structure,withstand,performance,limiting,factors,We,start,detailed,description,chemical,different,composi,phase,segregation,how,molecules,dyes,help,repair,structural,defects,overall,Moisture,result,passivation,through,low,dimensional,device,scalable,fab,rication,also,reviewed,challenges,degradation,design,implications,proposed,outlook,interpreted,ending,phrases,this

0.592558