典型文献
Unactivated C(sp3)-H functionalization via vinyl cations
文献摘要：
Direct functionalization of inert C(sp3)-H bonds is a topic of immense contemporary interest and exceptional value in organic synthesis.The recent research has established a novel and practical protocol which features the engagement of vinyl cation species to functionalize C(sp3)-H bonds.The discussion of the topic is arranged by the strategies to generate the reactive intermediates,including ionization of vinyl triflates,addition of electrophiles to alkynes,tandem cyclization of enynes or diynes,and decomposition of β-hydroxy-a-diazo ketones.This review closes with a personal perspective on the dynamic research area of unactivated C(sp3)-H functionalization via vinyl cations.Hopefully,it will provide timely illumination and beneficial guidance for organic chemists who are interested in this area.Meanwhile continued development of the field is strongly anticipated in the
文献关键词：
中图分类号：
作者姓名：
Xi-Jia Liu;Yin Xu;Conghui Tang;Peng-Cheng Qian;Long-Wu Ye
作者机构：
Key Laboratory of Environmental Functional Materials Technology and Application of Wenzhou City,College of Chemistry & Materials Engineering,Institute of New Materials & Industry Technology,Wenzhou University,Wenzhou 325035,China;Key Laboratory of Chemical Biology of Fujian Province,State Key Laboratory of Physical Chemistry of Solid Surfaces,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China;State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China
文献出处：
引用格式：
[1]Xi-Jia Liu;Yin Xu;Conghui Tang;Peng-Cheng Qian;Long-Wu Ye-.Unactivated C(sp3)-H functionalization via vinyl cations)[J].中国科学:化学（英文版）,2022(01):20-30
A类：
Unactivated,triflates,diynes
B类：
sp3,functionalization,via,vinyl,cations,Direct,inert,bonds,topic,immense,contemporary,exceptional,value,organic,synthesis,recent,research,has,established,novel,practical,protocol,which,features,engagement,species,functionalize,discussion,arranged,by,strategies,generate,reactive,intermediates,including,ionization,addition,electrophiles,alkynes,tandem,cyclization,enynes,decomposition,hydroxy,diazo,ketones,This,review,closes,personal,perspective,dynamic,area,unactivated,Hopefully,will,provide,timely,illumination,beneficial,guidance,chemists,who,interested,this,Meanwhile,continued,development,field,strongly,anticipated
AB值：
0.647801
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