典型文献
Hyperbranched phthalocyanine enabling black-phase formamidinium perovskite solar cells processing and operating in humidity open air
文献摘要：
The extreme instability of pure α-phase FAPbI3 under high humidity conditions restricts the high-throughput fabrication in unmodified air environments,resulting in poor performance of α-phase FAPbl3 perovskite devices obtained by scalable fabrication methods.Here we synthesized hyperbranched copper phthalocyanine(HCuPc)as a supramolecular additive with twisted phthalocyanine units to real-ize the molecular-level encapsulation at the grain boundaries through supramolecular interaction,which greatly broadened the processing window of FAPbI3 under high humidity.At the same time,unlike tra-ditional encapsulation layer that carrier can only be collected by tunneling effect,the twisted phthalocya-nine ring of HCuPc in perovskite films is more conducive to hole extraction.Finally,a record efficiency was achieved in pure FAPbI3 based inverted structured solar cell by blade-coating to the best of our knowledge,even under unmodified humid air conditions(relative humidity of 65％-85％).The best oper-ational stability of 3D pure FAPbl3 devices can also be achieved at the same time and unencapsulated HCuPc-FAPbI3 device can even operate with negligible degradation for 100 h in the open air(RH 30％-40％).
文献关键词：
中图分类号：
作者姓名：
Rong Li;Jiale Ding;Xijiao Mu;Yifei Kang;Anran Wang;Weihui Bi;Yunhe Zhang;Jing Cao;Qingfeng Dong
作者机构：
State Key Laboratory of Supramolecular Structure and Materials,College of Chemistry,Jilin University,Changchun 130012,Jilin,China;Engineering Research Center of Super Engineering Plastics,Ministry of Education,College of Chemistry,Jilin University,Changchun 130012,Jilin,China;State Key Laboratory of Applied Organic Chemistry,Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province,College of Chemistry and Chemical Engineering,Lanzhou University,Lanzhou 730000,Gansu,China
文献出处：
引用格式：
[1]Rong Li;Jiale Ding;Xijiao Mu;Yifei Kang;Anran Wang;Weihui Bi;Yunhe Zhang;Jing Cao;Qingfeng Dong-.Hyperbranched phthalocyanine enabling black-phase formamidinium perovskite solar cells processing and operating in humidity open air)[J].能源化学,2022(08):141-149
A类：
FAPbl3,HCuPc,phthalocya
B类：
Hyperbranched,phthalocyanine,enabling,black,phase,formamidinium,perovskite,solar,cells,processing,operating,humidity,open,air,extreme,instability,pure,FAPbI3,under,high,conditions,restricts,throughput,fabrication,unmodified,environments,resulting,poor,performance,devices,obtained,by,scalable,methods,Here,we,synthesized,hyperbranched,copper,supramolecular,additive,twisted,units,real,level,encapsulation,grain,boundaries,interaction,which,greatly,broadened,window,At,same,unlike,ditional,layer,that,carrier,can,only,collected,tunneling,effect,ring,films,more,conducive,hole,extraction,Finally,record,efficiency,was,achieved,inverted,structured,blade,coating,best,our,knowledge,even,relative,ational,also,unencapsulated,operate,negligible,degradation,RH
AB值：
0.531522
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