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典型文献
Round-the-clock water harvesting from dry air using a metal-organic framework
文献摘要:
Harvesting water from the atmosphere is an important process to solve the extreme lack of water resources in arid regions.Adsorption-based atmospheric water harvesting(AWH)takes advantage of solar thermal energy to harvest water from air.This technique is particularly suitable for arid regions characterized by low humidity and an abundance of sunshine.Nonetheless,under low humidity condi-tions,AWH is highly dependent on water-adsorbing materials exhibiting excellent performance.In this work,a metal-organic framework(MOF),namely[Zn2(bpy)(btec)(H2O)2]·2H2O,also denoted as MWH-1,was investigated for application in water harvesting under low humidity conditions(<20%).Notably,MWH-1 displayed outstanding water and thermal stability.At temperatures of 293-333 K and low pres-sure,activated MWH-1 a exhibited competitive water uptake(relative humidity(RH)=5%,uptake>200 cm3cm-3;RH=10%,uptake>250 cm3·cm-3).This ensured effective water harvesting at high temperatures during the day.In situ powder X-ray diffraction and Fourier-transform infrared analyses confirmed the sensitive water adsorption process of MWH-1 a.The X-ray single-crystal study further demonstrated that single-crystal structures could be completely restored following water harvesting.MWH-1 showed good structural stability and enabled water harvesting under low humidity and high temperature conditions.Thus,it has the potential for application in round-the-clock water harvesting in extremely arid regions.
文献关键词:
作者姓名:
Jianhui Li;Yi Wang;Yang Chen;Qizhao Xiong;Jiangfeng Yang;Libo Li;Jinping Li
作者机构:
College of Chemistry and Chemical Engineering,Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization,Taiyuan University of Technology,Taiyuan 030024,China;Key Laboratory of Coal Science and Technology,Ministry of Education and Shanxi Province,Taiyuan University of Technology,Taiyuan 030024,China
引用格式:
[1]Jianhui Li;Yi Wang;Yang Chen;Qizhao Xiong;Jiangfeng Yang;Libo Li;Jinping Li-.Round-the-clock water harvesting from dry air using a metal-organic framework)[J].中国化学工程学报(英文版),2022(09):170-177
A类:
AWH,btec,cm3cm
B类:
Round,clock,water,harvesting,from,dry,air,using,metal,organic,framework,Harvesting,atmosphere,important,process,solve,lack,resources,arid,regions,Adsorption,atmospheric,takes,advantage,solar,thermal,energy,This,technique,particularly,suitable,characterized,by,humidity,abundance,sunshine,Nonetheless,under,highly,dependent,adsorbing,materials,exhibiting,excellent,performance,In,this,MOF,namely,Zn2,bpy,2H2O,also,denoted,MWH,was,investigated,application,conditions,Notably,displayed,outstanding,stability,At,temperatures,pres,activated,exhibited,competitive,uptake,relative,RH,ensured,effective,during,day,situ,powder,ray,diffraction,Fourier,transform,infrared,analyses,confirmed,sensitive,adsorption,single,crystal,study,further,demonstrated,that,structures,could,be,completely,restored,following,showed,good,structural,enabled,Thus,has,potential,round,extremely
AB值:
0.529294
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