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The roles of MXenes in developing advanced lithium metal anodes
文献摘要:
Lithium(Li)metal has emerged as the most promising anode for rechargeable Li batteries owing to its high theoretical specific capacities,low negative electrochemical potential,and superior electrical con-ductivity.Replacing the conventional graphite anodes with Li metal anodes(LMAs)provides great poten-tial to exceed the theoretical limitations of current commercial Li-ion batteries,leading to next-generation high-energy-density rechargeable Li metal batteries(LMBs).However,further development of LMAs is hindered by several inherent issues,such as dangerous dendrite growth,infinite volume change,low Coulombic efficiency,and interfacial side reactions.MXenes,a family of two-dimensional(2D)transition metal carbides and/or nitrides,have recently attracted much attention to address these issues due to their 2D structure,lithiophilic surface terminations,excellent electrical and ionic conduc-tivity,and superior mechanical properties.Herein,an overview of recent advances in the roles of MXenes for stabilizing LMAs is presented.In particular,strategies of utilizing MXenes as the Li hosts,arti-ficial protection layers,electrolyte additives,and for separator modifications to develop stable and dendrite-free LMAs are discussed.Moreover,a perspective on the current challenges and potential out-looks on MXenes for advanced LMAs is provided.
文献关键词:
作者姓名:
Nicolas Lucero;Dayannara Vilcarino;Dibakar Datta;Meng-Qiang Zhao
作者机构:
Department of Chemical and Materials Engineering,Newark College of Engineering,New Jersey Institute of Technology,Newark,NJ 07103,USA;Jose Marti Stem Academy,Union City,NJ 07087,USA;Department of Mechanical and Industrial Engineering,Newark College of Engineering,New Jersey Institute of Technology,Newark,NJ 07103,USA
文献出处:
引用格式:
[1]Nicolas Lucero;Dayannara Vilcarino;Dibakar Datta;Meng-Qiang Zhao-.The roles of MXenes in developing advanced lithium metal anodes)[J].能源化学,2022(06):132-149
A类:
B类:
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AB值:
0.624757
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