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典型文献
Multifunctional high-fluorine-content molecule with high dipole moment as electrolyte additive for high performance lithium metal batteries
文献摘要:
Lithium metal batteries(LMBs)have been regarded as the most promising technology beyond lithium-ion batteries to meet the ever-increasing demand for high-energy and high-power secondary battery technologies.Challenges such as poor electrochemical stability of electrolytes,dendritic Li plating,gradual cathode structure degradation,and the resultant low Coulombic efficiency and short cycling life,however,have plagued the extended commercialization of LMBs.Here,a high-fluorine content and high dipole moment molecule,bisfluoroacetamide(BFA),was designed by Ma and his co-workers as an electrolyte additive for LMBs.This molecule could modify the sol-vation structure of Li ions and form a gradient solid elec-trolyte interphase on the anode side with tailored Li+adsorption and diffusion,and cathode electrolyte inter-phase layer before the decomposition of other carbonate solvents,enabling dendrite-free Li anodes and LMBs with long cycling life and excellent rate performance.This work explores a new approach to multifunctional electrolyte additive development and can also be adapted to other metal battery chemistries.
文献关键词:
作者姓名:
Xi Tang;Wen-Chao Zhang;Liu-Yue Cao
作者机构:
Institute of Environmental Engineering,School of Metallurgy and Environment,Central South University,Changsha 410083,China;School of Chemical and Biomolecular Engineering,the University of Sydney,Darlington,NSW 2006,Australia
引用格式:
[1]Xi Tang;Wen-Chao Zhang;Liu-Yue Cao-.Multifunctional high-fluorine-content molecule with high dipole moment as electrolyte additive for high performance lithium metal batteries)[J].稀有金属(英文版),2022(03):726-729
A类:
bisfluoroacetamide,Li+adsorption
B类:
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AB值:
0.564674
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