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典型文献
Room-temperature liquid metal engineered iron current collector enables stable and dendrite-free sodium metal batteries in carbonate electrolytes
文献摘要:
Metallic sodium(Na)is believed to be a promising anode material for sodium-ion batteries(SIBs)due to its low electrochemical potential,high theoretical specific capacity,superior electrical conductivity,and so on.However,issues such as high chemical activity,the growth of Na dendrites,large volume change,and unstable interface impede its practical application.We design a cheap iron(Fe)-based substrate dec-orated by a thin liquid metal Ga layer for stable and dendrite-free Na metal anodes in low-cost carbonate electrolytes.The inherent mechanism of Ga-based liquid metal in inhibiting the growth of Na dendrites was revealed for the first time.Liquid metal Ga with sodiophilic property can act as nucleation seeds to decrease the nucleation barrier and induce homogeneous Na+flux,resulting in uniform and dendrite-free Na deposition.Full cells with Na3V2(PO4)3 cathode were also assembled to verify the practical application ability of the modified Na metal anode.Under the regulation of the liquid metal layer,the Coulombic ef-ficiency,cycling life,and capacity of batteries are obviously enhanced.The strategy proposed here cannot only reduce the cost of batteries but also improve their electrochemical and safety performance.
文献关键词:
作者姓名:
Chuanliang Wei;Liwen Tan;Yuchan Zhang;Huiyu Jiang;Baojuan Xi;Shenglin Xiong;Jinkui Feng
作者机构:
Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials(Ministry of Education),Research Center for Carbon Nanomaterials,School of Materials Science and Engineering,Shandong University,Jinan 250061,China;School of Chemistry and Chemical Engineering,Shandong University,Jinan 250100,China
引用格式:
[1]Chuanliang Wei;Liwen Tan;Yuchan Zhang;Huiyu Jiang;Baojuan Xi;Shenglin Xiong;Jinkui Feng-.Room-temperature liquid metal engineered iron current collector enables stable and dendrite-free sodium metal batteries in carbonate electrolytes)[J].材料科学技术(英文版),2022(20):156-165
A类:
orated,Na+flux
B类:
Room,temperature,liquid,metal,engineered,iron,current,collector,enables,free,sodium,batteries,carbonate,electrolytes,Metallic,believed,promising,material,SIBs,due,its,low,electrochemical,potential,high,theoretical,specific,capacity,superior,electrical,conductivity,However,issues,such,activity,growth,dendrites,large,volume,change,unstable,interface,impede,practical,application,We,design,cheap,substrate,by,thin,Ga,layer,anodes,cost,inherent,mechanism,inhibiting,was,revealed,first,Liquid,sodiophilic,property,nucleation,seeds,decrease,barrier,induce,homogeneous,resulting,uniform,deposition,Full,cells,Na3V2,PO4,cathode,were,also,assembled,verify,ability,modified,Under,regulation,Coulombic,ef,ficiency,cycling,life,are,obviously,enhanced,strategy,proposed,cannot,only,reduce,but,improve,their,safety,performance
AB值:
0.564996
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